The correlated band theory methods, the around-mean-field LDA + U and dynamical LDA + HIA (Hub-bard-I), are applied to investigate the electronic structure of Pu chalcogenides. The LDA + U calculations for PuX (X = S, Se, Te) provide non-magnetic ground state in agreement with the experimental data. Non-integer filling of 5f-manifold (from approx. 5.6 in Pus to 5.7 PuTe). indicates a mixed valence ground state which combines f(5) and f(6) multiplets. Making use of the dynamical LDA+HIA method the photoelectron spectra are calculated in good agreement with experimental data. The three-peak feature near E-F attributed to 5f-manifold is well reproduced by LDA + HIA, and follows from mixed valence character of the ground state.
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