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Effects of high pressure thermal treatments in oxygen and helium atmospheres on amorphous silicon dioxide and its radiation hardness

机译:氧气和氦气气氛中高压热处理对非晶态二氧化硅及其辐射硬度的影响

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摘要

The effects of thermal treatments at similar to 400 degrees C in oxygen or helium atmospheres at similar to 180 baron the radiation hardness of amorphous SiO2 are studied. The generation efficiency of several point defects under gamma irradiation is compared to that of the untreated material. All the effects on point defects generation here observed can be explained in terms of changes in the precursor sites. In particular it has been observed that the thermal treatments can change the precursors sites of point defects both through temperature and pressure related processes, not depending on the atmosphere, and through oxygen related processes creating oxygen excess sites. The presence of dissolved oxygen also inhibits some hydrogen related processes, as the generation of H(l) centers, probably by activating different reactions paths for hydrogen.
机译:研究了在氧气或氦气气氛中,类似于180 bar的条件下,在类似于400℃的温度下进行热处理对非晶SiO2辐射硬度的影响。将γ射线照射下几个点缺陷的产生效率与未处理材料的产生效率进行了比较。此处观察到的所有对点缺陷产生的影响都可以通过前体位点的变化来解释。特别地,已经观察到,热处理可以通过与温度和压力有关的过程(不取决于大气)以及通过与氧有关的过程来改变点缺陷的前体位点,所述与氧有关的过程产生氧过量位点。溶解氧的存在还抑制了一些与氢有关的过程,因为H(l)中心的生成可能是通过激活氢的不同反应路径来实现的。

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