Synthesis and properties of n-type triphenylpyridine derivatives and applications in deep-blue organic light-emitting devices as electron-transporting layer

摘要

Two series of n-type triphenylpyridine derivatives with good thermal properties and efficient deep-blue emissions were designed, synthesized and systematically characterized. Most of them show high glass transition temperatures (T_g > 100 °C), relatively high electron mobilities, large ionization potentials (IP > 6.31 eV) and suitable electron affinities (EA > 2.93 eV) for facilitating efficient electron-injection. These attributes of the n-type triphenylpyridine derivatives favours their applications in organic light-emitting devices (OLEDs) as electron-transporting and hole-blocking materials (ETMs and HBMs). With these new materials, deep-blue OLEDs with a configuration of indium-tin oxide (ITO)/α-napthylphenylbiphenyl diamine (NPB)/9,10-di(2-naphthyl)anthracene (ADN)/triphenylpyridine derivative/LiF/MgAg were fabricated to investigate the properties of these triphenylpyridine derivatives as ETMs and HBMs. The devices show higher efficiency (2.54 cd A~(-1)), and better color purity (0.15, 0.10) compared to those of similarly-structured blue OLEDs using state-of-the-art ETMs. The large IP and deep-blue emission of the triphenylpyridine derivatives are considered to be key factors for the higher efficiencies and better color purity. Optical and other properties of the compounds are discussed in terms of their molecular structures.