Realization of the welding of individual TiO2 semiconductor nano-objects using a novel 1D Au80Sn20 nanosolder

摘要

Individual semiconductor nanowires (NWs) TiO2 were successfully welded together using novel one-dimensional (1D) Au80Sn20 (mass ratio) nanosolders at the nano-scale for the first time. The nanosolders were electrodeposited into nanoporous templates to form a 1D structure, and their morphology, crystal structure, chemistry and elemental electronic states were systematically characterized. Individual Au80Sn20 nanowires were proved to consist of mixed crystal phases, including a Au5Sn phase with a trigonal structure, a AuSn phase with a hexagonal structure and a small SnO2 phase produced the by oxidation of the surface portion. Chemical analysis indicated that the composition was Au80Sn20. The testing of the welding capability by either in situ TEM or in situ SEM by nanomanipulators and infiltration experiment revealed a good wet ability and diffusion ability between the Au80Sn20 nanosolder and the TiO2 nanowire. It is believed that our study contributes to the field a special nanosolder for future nano-scale welding techniques, which also make the bonding of titanium-based semiconductor oxide nanomaterials at the nano-scale a reality.