Improvement of Charge-Discharge Characteristics of the Mg-Ni Powder Electrodes at 55℃

摘要

Magnesium-nickel (Mg-Ni) powders are used as the anode materials for secondary lithium (Li) ion batteries.Mg-Ni powders with ratios of 1: 1 (Mg:Ni) are prepared and their structure and electrochemical behavior at room temperature and 55℃ are investigated. The results show that adding Ni powders to Mg powders can reduce the charge-discharge capacities and improve cycling life. In charge-discharge cycle testing at 55℃, the Li ion concentration gradually increased with increasing the duration of electrochemical reactions, indicating that the charge-discharge capacities increase with increment of cycling number. The formation of a solid electrolyte interface (SEI) layer restrains Mg ions from dissolving into the electrolyte and thus improves the charge-discharge capacities at high temperature.