首页> 外文期刊>Journal of nanoscience and nanotechnology >La_(0.3)Sr_(0.2)Mn_(0.1)Zn_(0.4) Oxide-Sm_(0.2)Ce_(0.8)O_(1.9) (LSMZ-SDC) Nanocomposite Cathode for Low Temperature SOFCs
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La_(0.3)Sr_(0.2)Mn_(0.1)Zn_(0.4) Oxide-Sm_(0.2)Ce_(0.8)O_(1.9) (LSMZ-SDC) Nanocomposite Cathode for Low Temperature SOFCs

机译:用于低温SOFC的La_(0.3)Sr_(0.2)Mn_(0.1)Zn_(0.4)氧化物-Sm_(0.2)Ce_(0.8)O_(1.9)(LSMZ-SDC)纳米复合阴极

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摘要

Nanocomposite based cathode materials compatible for low temperature solid oxide fuel cells (LTSOFCs) are being developed. In pursuit of compatible cathode, this research aims to synthesis and investigation nanocomposite La_(0.3)Sr_(0.2)Mn_(0.1)Zn_(0.4) oxide-Sm_(0.2)Ce_(0.8)O_(1.9) (LSMZ-SDC) based system. The material was synthesized through wet chemical method and investigated for oxide-ceria composite based electrolyte LTSOFCs. Electrical property was studied by AC electrochemical impedance spectroscopy (EIS). The microstructure, thermal properties, and elemental analysis of the samples were characterized by TGA/DSC, XRD, SEM, respectively. The AC conductivity of cathode was obtained for 2.4 Scm~(-1) at 550 ℃ in air. This cathode is compatible with ceria-based composite electrolytes and has improved the stability of the material in SOFC cathode environment.
机译:正在开发与低温固体氧化物燃料电池(LTSOFC)兼容的基于纳米复合材料的阴极材料。为了寻求相容的阴极,本研究旨在合成和研究基于La_(0.3)Sr_(0.2)Mn_(0.1)Zn_(0.4)氧化物-Sm_(0.2)Ce_(0.8)O_(1.9)(LSMZ-SDC)的纳米复合材料系统。该材料是通过湿化学方法合成的,并用于氧化物-二氧化铈复合材料电解质LTSOFC。通过AC电化学阻抗谱(EIS)研究电性能。分别用TGA / DSC,XRD,SEM表征了样品的微观结构,热性能和元素分析。在空气中550℃下,阴极的交流电导率为2.4 Scm〜(-1)。该阴极与二氧化铈基复合电解质兼容,并提高了材料在SOFC阴极环境中的稳定性。

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