Preparation and Optical Limiting Properties of Polyurethane Containing Long Conjugated Chromophores

摘要

Two functional polyurethanes (P1 and P2) bearing a large electron conjugated chromophoric pendant were synthesized and characterized by FT-IR, 1H-NMR and UV-Vis absorption spectra. Their optical limiting properties were evaluated. The results show that P1 and P2 show novel optical limiting properties, which are assigned to a long electron conjugated chromophoric pendant. It was found that their optical limiting properties were affected simultaneously by solution concentration and P2 displays a better optical limiting property than P1 at the same solution transmittance, although that P1 has larger (3) (4.28×10~(-11) esu) than P2 (0.87×10~(-11) esu), and their optical limiting mechanism is investigated.