首页> 外文期刊>Journal of Macromolecular Science. Physics >Influence of Reactive Compatibilizer on the Morphology, Rheological, and Mechanical Properties of Recycled Poly(Ethylene Terephthalate)/Polyamide 6 Blends
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Influence of Reactive Compatibilizer on the Morphology, Rheological, and Mechanical Properties of Recycled Poly(Ethylene Terephthalate)/Polyamide 6 Blends

机译:反应性增容剂对再生聚对苯二甲酸乙二酯/聚酰胺6共混物形态,流变学和力学性能的影响

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摘要

Recycled poly(ethylene terephthalate) (R-PET) and virgin polyamide 6 (PA6) blends compatibilized with glycidyl methacrylate grafted poly(ethylene-octene) (POE-g-GMA) were melt blended. The morphological, rheological and mechanical properties of the prepared blends were investigated by scanning electron microscopy, rheology, and an electromechanical testing instrument, respectively. All of the blends showed a droplet dispersion type morphology, and the PA6 particle size decreased with increase in the POE-g-GMA concentration. The storage modulus (G′), loss modulus (G″), and complex viscosity (η?) of the blends significantly increased at low frequency with the addition of POE-g-GMA. In addition, “Cole-Cole” plots showed that the elasticity of the blends was also increased by raising the compatibilizer dosage. It was also found that 10 wt% of POE-g-GMA caused 88.46 and 171.05% increments in Charpy impact strength and elongation at break with only a 21.66% decrement in tensile strength.
机译:将相容于甲基丙烯酸缩水甘油酯接枝的聚(乙烯-辛烯)(POE-g-GMA)的再生聚对苯二甲酸乙二醇酯(R-PET)和纯聚酰胺6(PA6)混合物进行共混。分别通过扫描电子显微镜,流变学和机电测试仪器研究了所制备共混物的形态,流变和机械性能。所有共混物均表现出液滴分散型形态,并且随着POE-g-GMA浓度的增加,PA6粒径减小。随着POE-g-GMA的添加,共混物的储能模量(G'),损耗模量(G'')和复数粘度(ηη)在低频下显着增加。另外,“ Cole-Cole”图表明,通过增加相容剂的用量,共混物的弹性也增加了。还发现10重量%的POE-g-GMA引起夏比冲击强度和断裂伸长率的增加88.46和171.05%,而抗张强度仅减少21.66%。

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