Numerical simulation of reactive extrusion processes for activated anionic polymerization

摘要

In order to deal with the complicated relationships among the variables of the reactive extrusion process for activated anionic polymerization, a three-dimensional equivalent model of closely intermeshing co-rotating twin screw extruders was established. Then the numerical computation expressions of the monomer concentration, the monomer conversion, the average molecular weight and the fluid viscosity were deduced, and the numerical simulation of the reactive extrusion process of styrene was carried out. At last, our simulated results were compared with Michaeli's simulated results and experimental results.