The synthesis and characterization of melamine based Schiff bases and its trinuclear [salen/salophenFe(III)] and [salen/salophenCr(III)] capped complexes

摘要

Four new trinuclear Fe(III) and Cr(HI) complexes involving tetradentate Schiff bases N, N'-bis(sali-cylidene)ethylenediamine-(salenH2) or bis(salicylidene)-o-phenylenediamine-(salophen H2) with 2,4,6-tris(4-carbo-xybenzimino)-1,3,5-triazine have been synthesized and characterized by means of elemental analysis, ~1H NMR, FT-IR spectroscopy, LC-MS, thermal analyses and magnetic susceptibility measurements. The complexes have also been characterized as low-spin distorted octahedral Fe(III) and Cr(III) bridged by COO~- group.