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A pressure solution creep law for quartz from indentation experinients

机译:压痕经验的石英压力解蠕变律

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Indenter experiments have been performed on quartz crystals in order to establish a pressure solution creep law relevant at upper to middle crustal conditions. This deformation mechanism contributes to Earth's crust geodynamics, controlling processes as different as fault permeability, strength, and stress evolution during interseismic periods or mechanochemical differentiation during diagenesis and metamorphism. Indenter experiments have been performed at 350°C and 20-120 MPa during months with differential stress varying from 25 to 350 MPa. Several experimental parameters were varied: nature of quartz (synthetic or natural), nature of fluid, manner in which the solid/ solution/solid interface was filled, and orientation of the indented surfaces versus quartz crystallographic c axis. Significant strain rates could only be obtained when using high-solubility solutions (NaOH 1 mol L~(-1)). Displacement rates of the indenter were found activated by differential stress, with exponential dependence, as theoretically predicted. The mean thickness of the trapped fluid phase below the indenter was estimated in the range 2-10 nm. Moreover, the development of this trapped fluid phase was relatively fast and allowed fluid penetration into previously dry contact regions by marginal dissolution. The indenter displacement rate was driven by differential stress, and its kinetics was controlled by diffusion along the trapped fluid and the development of a morphological roughness along the interface. Conversely, marginal strain energy driven dissolution was observed around the indenter, and its kinetics was controlled by free-surface reaction. These experimental results are applied to model the interactions between pressure solution and brittle processes in fault zones, providing characteristic time scales for postseismic transitory creep and sealing processes in quartz-rich rocks.
机译:为了建立与上,中地壳条件有关的压力解蠕变定律,已经对石英晶体进行了压头实验。这种变形机制有助于地壳的地球动力学,控制过程如断层渗透率,强度和间震期间的应力演化或成岩作用和变质作用期间的机械化学分化。压头实验已在350°C和20-120 MPa的压力下进行了数月,压差在25到350 MPa之间变化。改变了几个实验参数:石英的性质(合成的或天然的),流体的性质,填充固体/溶液/固体界面的方式以及凹入的表面相对于石英晶体c轴的方向。仅在使用高溶解度溶液(NaOH 1 mol L〜(-1))时才能获得较大的应变率。如理论上预测的那样,发现压头的位移速率是由具有指数依赖性的差应力激活的。压头下方的截留流体相的平均厚度估计为2-10 nm。此外,这种捕获的流体相的发展相对较快,并且通过边际溶解使流体渗透到先前干燥的接触区域中。压头位移速率是由微分应力驱动的,其动力学是由沿捕获流体的扩散和沿界面的形态粗糙度的发展控制的。相反,在压头周围观察到边缘应变能驱动的溶解,其动力学受自由表面反应控制。这些实验结果被用于模拟压力解与断裂带中脆性过程之间的相互作用,为富石英岩中地震后的瞬态蠕变和封闭过程提供了特征性的时标。

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