Single-particle laser-induced-fluorescence spectra of biological and other organic-carbon aerosols in the atmosphere: Measurements at New Haven, Connecticut, and Las Cruces, New Mexico

摘要

This study focuses on organic carbon (OC) aerosols, including natural biological aerosols, in the Earth's troposphere, and on laser-induced fluorescence (LIF) spectral methods for studying these aerosols. LIF spectra of atmospheric OC and biological aerosols (having diameters greater than approximately 3 μm) measured at New Haven, Connecticut, and Las Cruces, New Mexico, are reported. A hierarchical clustering method was used to cluster approximately 90% of the single-particle LIF spectra into 8–10 groups. Some of these groups have spectra that are similar to spectra of some important classes of atmospheric aerosol, such as humic/fulvic acids and humic-like substances, bacteria, cellulose, marine aerosol, and polycyclic aromatic hydrocarbons (PAH). A comparison with previous measurements made at Adelphi, Maryland, reveals that the most highly populated clusters found at Adelphi, and some of the less populated ones, also appear in the LIF spectra at New Haven and Las Cruces, even though the regional climates at these locations is different (New England/Atlantic Coastal, for New Haven and Adelphi, and Chihuahuan Desert for Las Cruces), and the measurements were made in different seasons. The results are consistent with some (perhaps most) of the fluorors in OC and biological atmospheric aerosols being common to these three sites. On average, spectra characteristic of humic/fulvic acids and humic-like substances (HULIS) comprise 28–43% of fluorescent particles at all three sites; whereas cellulose-like spectra contribute only 1–3%.