Binary phase diagram series : 1,3,3-trinitroazetidine (TNAZ)/1,3,5-trinitrobenzene (TNB)

摘要

The binary phase diagram for the 1,3,3-trinitroazetidine (TNAZ)/1,3,5-Trinitrobenzene (TNB) system has been predicted computationally and determined experimentally. Mixtures exhibit the thermal characteristics associated with a simple binary eutectic system affected by both non-ideal behavior of the two components and observable polymorphism associated only with TNB. Experimental eutectic temperature/composition (deg C/mol percent TNAZ) values in the binary mixtures believed to contain one or more of the TNB polymorphic modifications, I, III and IV, are 68.4/53.4, 63.6/47.8 and 62.0/45.6, respectively.