Mgl_2 etherate-catalysed Strecker reaction: a facile and efficient synthesis of a-aminonitriles from aldimines and trimethylsilyl cyanide

Yongping Lu; Yanping Wang; Xingxian Zhang

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Mgl_2 etherate-catalysed Strecker reaction: a facile and efficient synthesis of a-aminonitriles from aldimines and trimethylsilyl cyanide

机译：Mgl_2醚催化的Strecker反应：由醛亚胺和三甲基甲硅烷基氰化物快速高效合成a-氨基腈

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摘要

A mild and efficient procedure for the synthesis of a-aminonitriles is achieved by treatment of aldimines with trimethylsilyl cyanide catalysed by Mgl_2 etherate.

机译：通过用Mgl_2醚化物催化的三甲基甲硅烷基氰化物处理醛亚胺，可以实现温和而有效的合成α-氨基腈的方法。

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《Journal of chemical research: reviews and research papers from all branches of chemistry》 |2013年第11期|共3页
作者
Yongping Lu; Yanping Wang; Xingxian Zhang;
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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
aldimines; trimethylsilyl cyanide; Strecker; MgI_2 etherate;

机译：醛亚胺;三甲基甲硅烷基氰化物;Strecker;MgI_2醚化物;

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1. Mgl_2 etherate-catalysed Strecker reaction: a facile and efficient synthesis of a-aminonitriles from aldimines and trimethylsilyl cyanide [J] . Yongping Lu, Yanping Wang, Xingxian Zhang Journal of chemical research: reviews and research papers from all branches of chemistry . 2013,第11期

机译：Mgl_2醚催化的Strecker反应：由醛亚胺和三甲基甲硅烷基氰化物快速高效合成a-氨基腈
2. Enantioselective Strecker Reactions between Aldimines and Trimethylsilyl Cyanide Promoted by Chiral N,N'-Dioxides [J] . Zhigang Jiao, Xiaoming Feng, Bo Liu, European journal of organic chemistry . 2003,第19期

机译：手性N，N'-二氧化物促进的醛亚胺与氰化三甲基甲硅烷基之间的对映选择性斯特雷克反应
3. One-pot synthesis of α-aminonitriles from alkyl and aryl cyanides: a Strecker reaction via aldimine alanes [J] . Szabolcs Sipos, Istvan Jablonkai Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2009,第16期

机译：一锅法从烷基和芳基氰化物合成α-氨基腈：通过醛亚胺丙氨酸的Strecker反应
4. Catalytic Enantioselective Synthesis of α,α-Disubstituted Amino Acids: The Strecker Reaction of Ketimines Using Chiral Poly-Gadolinium Complexes [C] . Masakatsu Shibasaki, Motomu Kanai Asymmetric synthesis and application of α-amino acids . 2007

机译：催化对映选择性合成α，α-二取代氨基酸：手性聚Poly配合物对酮亚胺的斯特雷克反应
5. Hypercoordinate silicon compounds in organic synthesis: Improved methods for the synthesis of aryl(trialkoxy)silane derivatives; and trimethylsilyl cyanide as a cyanide source for nucleophilic substitution. [D] . Manoso, Amy Slover. 2004

机译：有机合成中的超配位硅化合物：合成芳基（三烷氧基）硅烷衍生物的改进方法；三甲基甲硅烷基氰化物作为亲核取代的氰化物来源。
6. 1-Ethyl-3-methylimidazolium acetate as a highly efficient organocatalyst for cyanosilylation of carbonyl compounds with trimethylsilyl cyanide [O] . Bakhtar Ullah, Jingwen Chen, Zhiguo Zhang, -1

机译：1-乙基-3-甲基咪唑乙酸盐作为高效的有机催化剂用于羰基化合物与三甲基甲硅烷基氰化物的氰基硅烷化
7. Enantioselective Strecker reactions between aldimines and trimethylsilyl cyanide promoted by chiral N,N '-dioxides [O] . Jiao ZG, Feng XM, Liu B, 2003

机译：手性N，N'-二氧化物促进醛亚胺与三甲基甲硅烷基氰化物之间的对映选择性斯特雷克反应
8. Reactions of Carbon Monoxide with Trimethylsilyl and Tris(trimethylsilyl)silyl Derivatives of Group 4 Metals. Synthesis, Characterization, and Reactivity of Silaacyl Complexes [R] . Campion, B. K., Falk, J., Tilley, T. D. 1987

机译：一氧化碳与第3族金属的三甲基甲硅烷基和三（三甲基甲硅烷基）甲硅烷基衍生物的反应。 silaacyl配合物的合成，表征和反应性

Mgl_2 etherate-catalysed Strecker reaction: a facile and efficient synthesis of a-aminonitriles from aldimines and trimethylsilyl cyanide

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