Environmentally friendly catalysis using supported reagents: catalytic epoxidation with hydrogen peroxide mediated by iron(II) ions immobilised on gamma-alumina

Monfared HH.; Ghadimi M.

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Environmentally friendly catalysis using supported reagents: catalytic epoxidation with hydrogen peroxide mediated by iron(II) ions immobilised on gamma-alumina

机译：使用支持的试剂对环境友好的催化作用：由固定在γ-氧化铝上的铁（II）离子介导的过氧化氢催化环氧化

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A simple heterogeneous catalyst based on supporting iron(II) ions on gamma-alumina was developed and successfully applied to the selective epoxidation of olefins with 35% aqueous H2O2 as an oxygen donor in CH3CN. [References: 9]

机译：开发了一种基于在γ-氧化铝上负载铁（II）离子的简单多相催化剂，并将其成功应用于以35％的H2O2作为CH3CN的氧供体的烯烃的选择性环氧化。 [参考：9]

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《Journal of Chemical Research. Synopses》 |2003年第5期|共2页
作者
Monfared HH.; Ghadimi M.;
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正文语种 eng
中图分类化学;
关键词
Heterogenous catalyst; Hydrogen peroxide; Iron ions; Oxidation;

机译：非均相催化剂;过氧化氢;铁离子;氧化;

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1. Environmentally friendly catalysis using supported reagents: catalytic epoxidation with hydrogen peroxide mediated by iron(II) ions immobilised on gamma-alumina [J] . Monfared HH., Ghadimi M. Journal of Chemical Research. Synopses . 2003,第5期

机译：使用支持的试剂对环境友好的催化作用：由固定在γ-氧化铝上的铁（II）离子介导的过氧化氢催化环氧化
2. Environmentally friendly epoxidation of olefins under phase-transfer catalysis conditions with hydrogen peroxide [J] . YahdihMahha, Laurent Salles, Jean-Yves Piquemal Journal of Catalysis . 2007,第2期

机译：在相转移催化条件下用过氧化氢对烯烃进行环保的环氧化
3. Reagent-injection spectrophotometric determination of citric acid in beverages and pharmaceutical formulations based on its inhibitory effect on the iron(III) catalytic oxidation of 2,4-diaminophenol by hydrogen peroxide [J] . Demetrius G.Themelis, Paraskevas D.Tzanavaras Analytica chimica acta . 2001,第1期

机译：试剂注射分光光度法对过氧化氢对2,4-二氨基苯酚铁（III）催化氧化的抑制作用，用于饮料和药物制剂中柠檬酸的测定
4. Catalytic Olefin Epoxidation and Dihydroxylation with Hydrogen Peroxide in Common Ionic Liquids: Comparative Kinetics and Mechanistic Study [C] . Mahdi M. Abu-Omar, Gregory S. Owens, Armando Durazo, Symposium ionic liquids as green solvents: Progress and prospects . 2003

机译：常用离子液中过氧化氢催化烯烃环氧化和二羟基化：比较动力学和机械研究
5. Oxidation of humic substances by environmentally friendly oxidants iron(VI) and hydrogen peroxide. [D] . Lee, Changyoul. 2005

机译：腐殖质被环境友好的氧化剂铁（VI）和过氧化氢氧化。
6. Biomimetic Non-Heme Iron-Catalyzed Epoxidation of Challenging Terminal Alkenes Using Aqueous H2O2 as an Environmentally Friendly Oxidant [O] . Anja Fingerhut, Jorge Vargas-Caporali, Marco Antonio Leyva-Ramírez, 2019

机译：使用过氧化氢水溶液作为环境友好型氧化剂对具有挑战性的末端烯烃进行仿生非血红素铁催化的环氧化
7. Regioselectivity and Diasteroselectivity in Pt(II)-Mediated Green Catalytic Epoxidation of Terminal Alkenes with Hydrogen Peroxide: Mechanistic Insight into a Peculiar Substrate Selectivity [O] . -1

机译：PT（II）介导的聚烯烃和DiaSteroOSECTENTIVE与过氧化氢的末端烯烃的末端催化环氧化：机械洞察术语选择性
8. Electrocatalysis of Oxygen Reduction. Part III. Selective Reduction to Hydrogen Peroxide or Water Using Polymeric Attachment of Metalloporphyrins [R] . Bettelheim, A., Chan, R. J. H., Kuwana, T. 1979

机译：氧还原的电催化。第三部分。使用金属卟啉的聚合物连接选择性还原为过氧化氢或水

Environmentally friendly catalysis using supported reagents: catalytic epoxidation with hydrogen peroxide mediated by iron(II) ions immobilised on gamma-alumina

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