Crystal structure and spectroscopy of the low-spin iron(II) compound: tris(bipyrimidine)iron(II) bis(triflate), [Fe(bipym)_3](CF_3SO_3)_2

Gerard A. van Albada; Wilberth J. J. Smeets; Anthony L. Spek; Jan Reedijk

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Crystal structure and spectroscopy of the low-spin iron(II) compound: tris(bipyrimidine)iron(II) bis(triflate), [Fe(bipym)_3](CF_3SO_3)_2

机译：低旋转铁（II）化合物的晶体结构和光谱：三（联嘧啶）铁（II）双（三氟甲磺酸盐），[Fe（bipym）_3]（CF_3SO_3）_2

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The compound [Fe(bipym)_3](CF_3SO_3)_2 (in which bipym = 2,2'-bipyrimidine) crystallizes in the space group P2_1/c, with a = 13.7641(11), b = 18.7557(19), c = 12.3627(11) A, β = 103.085(8)° and Z = 4. The low-spin Fe(II) atom is octahedrally surrounded by six nitrogen atoms of three bipyrimidine groups with Fe-N distances that vary from 1.968(4) to 1.975(4) A. In the far-infrared region the Fe-N vibrations are observed at 359 and 372 cm~(-1).

机译：化合物[Fe（bipym）_3]（CF_3SO_3）_2（其中bipym = 2,2'-联嘧啶）在空间组P2_1 / c中结晶，a = 13.7641（11），b = 18.7557（19），c = 12.3627（11）A，β= 103.085（8）°，Z =4。低旋转的Fe（II）原子被三个Bipyrimidine基团的六个氮原子八面体包围，Fe-N距离从1.968（4）开始变化）至1.975（4）A。在远红外区域，在359和372 cm〜（-1）处观察到Fe-N振动。

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来源
《Journal of chemical crystallography》 |2000年第7期|共4页
作者
Gerard A. van Albada; Wilberth J. J. Smeets; Anthony L. Spek; Jan Reedijk;
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正文语种 eng
中图分类晶体学;
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2; 2'-bipyrimidine; low-spin; iron; crystal structure; infrared;

机译：2;2'-联嘧啶;低旋转;铁;晶体结构;红外;

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Crystal structure and spectroscopy of the low-spin iron(II) compound: tris(bipyrimidine)iron(II) bis(triflate), [Fe(bipym)_3](CF_3SO_3)_2

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