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首页> 外文期刊>Journal of chemical crystallography >Hydrothermal synthesis and X-ray structure: a reduced titanic molybdenum(V) phosphate (NH_3CH_2CH_2NH_2)_5Na [Ti_2Mo_(12)O_(30)(PO_4)(HPO_4)_4(H_2PO_4)_3]·6H_2O
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Hydrothermal synthesis and X-ray structure: a reduced titanic molybdenum(V) phosphate (NH_3CH_2CH_2NH_2)_5Na [Ti_2Mo_(12)O_(30)(PO_4)(HPO_4)_4(H_2PO_4)_3]·6H_2O

机译:水热合成与X射线结构:还原性钛酸钼(V)(NH_3CH_2CH_2NH_2)_5Na [Ti_2Mo_(12)O_(30)(PO_4)(HPO_4)_4(H_2PO_4)_3]·6H_2O

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摘要

A novel titanic molybdenum(V) phosphate (NH_3CH_2CH_2NH_2)_5Na [Ti_2Mo_(12)O_(30)(PO_4)(HPO_4)_4(H_2PO_4)_3]·6H_2O crystallizes in the triclinic space group P1 with a = 12.057(3) A, b = 14.668(2) A, c = 21.2680(10) A, α = 80.840(10)°, β = 82.960(10)°, γ = 76.65(2)°, D_c = 2.707 g cm~(-3) for Z = 2, Refinement based on 12,037 observed reflections led to R = 0.0609. The result of single crystal x-ray diffraction revealed the presence of a tunnel and two crystallographically independent clusters in the solid state structure. The plane layers in its solid-state structure are interconnected in-sheet (axial) through multipoint hydrogen bonding between the ethylenediamine nitrogen atoms and the cluster oxygen atoms.
机译:新型钛酸钛钼(V)(NH_3CH_2CH_2NH_2)_5Na [Ti_2Mo_(12)O_(30)(PO_4)(HPO_4)_4(H_2PO_4)_3]·6H_2O在三斜晶空间群P1中结晶,其a = 12.057(3)A ,b = 14.668(2)A,c = 21.2680(10)A,α= 80.840(10)°,β= 82.960(10)°,γ= 76.65(2)°,D_c = 2.707 g cm〜(-3 )对于Z = 2,基于观察到的12,037个反射进行细化,得出R = 0.0609。单晶X射线衍射的结果表明在固态结构中存在隧道和两个晶体学上独立的簇。固态结构中的平面层通过乙二胺氮原子和簇氧原子之间的多点氢键在片内(轴向)相互连接。

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