首页> 外文期刊>Journal of Chemical and Engineering Data: the ACS Journal for Data >Heat Capacities, Excess Enthalpies, and Volumes of Mixtures Containing Cyclic Ethers. 3. Binary Systems {Tetrahydrofuran, Tetrahydropyran, 1,4-Dioxane, or 1,3-Dioxolane + Cyclohexane or Toluene}
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Heat Capacities, Excess Enthalpies, and Volumes of Mixtures Containing Cyclic Ethers. 3. Binary Systems {Tetrahydrofuran, Tetrahydropyran, 1,4-Dioxane, or 1,3-Dioxolane + Cyclohexane or Toluene}

机译:含环醚的混合物的热容量,过量焓和体积。 3.二元系统{四氢呋喃,四氢吡喃,1,4-二恶烷或1,3-二恶戊烷+环己烷或甲苯}

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摘要

Excess molar volumes for {1,4-dioxane or 1,3-dioxolane + cyclohexane} and excess molar enthalpies and isobaric excess molar heat capacities for the binary mixtures {tetrahydrofuran, tetrahydropyran, 1,4-dixoane, or 1,3-dioxolane + cyclohexane or toluene} at the temperature 298015 K have been determined as a function of mole fraction. The magnitude of these experimental quantities is discussed in terms of the nature and type of intermolecular interactions in binary mixtures. When available, the results have been compared with literature values.
机译:{1,4-二氧六环或1,3-二氧戊环+环己烷}的摩尔体积过大,二元混合物{四氢呋喃,四氢吡喃,1,4-二氧六环或1,3-二氧戊环)的摩尔过量焓和等压过剩摩尔热容已经确定了在温度298015K下的+环己烷或甲苯}作为摩尔分数的函数。根据二元混合物中分子间相互作用的性质和类型讨论了这些实验量的大小。如果可用,将结果与文献值进行比较。

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