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首页> 外文期刊>Journal of Chemical and Engineering Data: the ACS Journal for Data >Measurement and Prediction of Excess Molar Enthalpies and Excess Molar Volumes of the Ternary System 1,3-Dichlorobenzene + Benzene + Hexane at 298.15 K
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Measurement and Prediction of Excess Molar Enthalpies and Excess Molar Volumes of the Ternary System 1,3-Dichlorobenzene + Benzene + Hexane at 298.15 K

机译:三元体系1,3-二氯苯+苯+己烷在298.15 K下的过量摩尔焓和过量摩尔体积的测量和预测

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摘要

Experimental excess molar enthalpies and excess molar volumes for the ternary system {x_1 1,3-dichlorobenzene + x_2benzene + (1- x_1-x_2) hexane} have been determined at the temperature of 298.15 K and atmospheric pressure.Values of excess molar enthalpies were measured using a Calvet microcalorimeter,and excess molar volumes were determined from the densities of the pure liquids and mixtures,using a vibrating-tube densimeter.Several empirical expressions for estimating ternary properties from experimental binary results were applied.
机译:在298.15 K的温度和大气压力下,确定了三元体系{x_1 1,3-二氯苯+ x_2苯+(1- x_1-x_2)己烷}的实验过量摩尔焓和过量摩尔体积。使用Calvet微量热量计进行测量,并使用振动管密度计从纯净液体和混合物的密度中确定过量的摩尔体积。使用了几个根据实验二元结果估算三元性质的经验表达式。

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