Design and development of a multichannel potentiometer for monitoring an electrode arrayt and its application in flow analysis

摘要

A versatile potentiometer that works with electrode arrays in flow injection and/or monosegmented flow systems is described. The potentiometer is controlled by a microcomputer that allows individual, sequential multiplexed or random accesses to eight electrodes while employing only one reference electrode. The instrument was demonstrated by monitoring an array of seven flow-through ion-selective electrodes for Ag~+ and for three electrodes for Cl~-, Ca~(2+) and K~+. The figures of merit of the individual and multilexed (summed) readings of the electrode array were compared. The absolute standard deviation of the measurements made by summing the potential of two or more electrodes was maintained constant, thus improving the precision of the measurement in the precision of individual measurements. The preliminary tests suggest that the system can allow for 270 determinations per hour, with a linear range from 1.0 X 10~(-2) to 1.0 X 10~(-4) mol l~(-1) for the three different analytes. Detection limits were estimated as 3.1 X 10~(-5), 3.0 X 10~(-6) and 1.0 X 10~(-5) mol l~(-1) for Cl~-, Ca~(2+) and K~+, respectively.