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Mechanical performance studies on extruded cornstarch-based plastic manufactures

机译:挤出的玉米淀粉基塑料制品的机械性能研究

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摘要

Twin-screw extrusion of cornstarch produces a strong, yet readily biodegradable plastic material. Because of the brittleness of these cornstarch plastics, ASTM standard methods did not apply, and an alternative sample grip was developed. A suitable method for the tensile testing of extruded cornstarch plastics of differing feed composition (amylose content, cross-linking, plasticizer) and processing conditions (temperature) was developed, and quantitative values of tensile strength, strain, elastic modulus, and energy were obtained. The mean tensile strength of these materials ranged from 667 to 4148 psi, which is in the range of values for low-density polyethylene and high-density polyethylene. The high amylose content cornstarch plastics extruded at high temperatures demonstrated greatest strength. Wet/dry studies of the pure cornstarch materials showed them to degrade readily with extended exposure to water, but immersion in water for 1 h in room temperature (17 °C) water did not, as measured by standard tensile tests, adversely affect their strength, but made them more ductile, less stiff and tougher.
机译:玉米淀粉的双螺杆挤出生产出结实而又易于生物降解的塑料。由于这些玉米淀粉塑料的脆性,ASTM标准方法不适用,因此开发了另一种样品夹具。开发了一种适用于不同进料组成(直链淀粉含量,交联剂,增塑剂)和加工条件(温度)的挤出玉米淀粉塑料拉伸试验的合适方法,并获得了拉伸强度,应变,弹性模量和能量的定量值。这些材料的平均拉伸强度在667至4148 psi的范围内,在低密度聚乙烯和高密度聚乙烯的值范围内。在高温下挤出的高直链淀粉含量的玉米淀粉塑料表现出最大的强度。对纯玉米淀粉材料的湿/干研究表明,长时间暴露于水后它们容易降解,但是按标准拉伸试验测得,在室温(17°C)的水中浸泡1小时不会对其强度产生不利影响,但使它们更具延展性,刚性和韧性降低。

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