Mechanical and thermal properties of starch-filled poly(D,L-lactic acid)/poly(hydroxy ester ether) biodegradable blends

摘要

The mechanical, structural, and thermal properties of injection-molded composites of granular cornstarch, poly(D,L-lactic acid) (PDLLA), and poly(hydroxy ester ether) (PHEE) were investigated. These composites had high tensile strengths, ranging from 17 to 66 MPa, at starch loadings of 0-70 wt %. Scanning electron microscopy micrographs of fracture specimens revealed good adhesion between the starch granule and the polymer matrix, as evidenced by broken starch granules. The adhesion of the starch granules to the polymer matrix was the greatest when the matrix PDLLA/PHEE ratios ranged from zero to unity. At a PDLLA/PHEE ratio of less than unity, as the starch content increased in the composites, there was an increase in the tensile strength and modulus, with a concurrent decrease in elongation. The effects of starch on the mechanical properties of starch/PDLLA composites showed that as the starch content of the composite increased, the tensile strength and elongation to break decreased, whereas Young's modulus increased. In contrast, the tensile strength of starch/PHEE composites increased with increasing starch content. (C) 2003 Wiley Periodicals, Inc. [References: 50]