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Role of 4-phenyl-3-buten-2-one in boar taint: Identification of newcompounds related to sensorial descriptors in pig fat

机译:4-苯基-3-丁烯-2-酮在公猪异味中的作用:鉴定与猪脂肪中感官描述有关的新化合物

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摘要

The possible contribution of other compounds to the development of boar taint in fat samples with low concentrations of skatole and androstenone and classified as tainted was evaluated by GC-MS in the SCAN mode. Skatole and androstenone were determined by normal phase HPLC and GC-MS, respectively. For the identification of other compounds fat samples were purified with a gel filtration column and the second fraction was saponified at room temperature with KOH/3 N MeOH. 4-Phenyl-3-buten-2-one was the main compound identified in the fat samples, and its identification was corroborated by comparison with a standard solution obtained from a commercial source and by HPLC. The sensorial analysis of 4-phenyl-3-buten-2-one showed its possible contribution to boar taint. The possible contribution of phenol derivatives and short-chain fatty acids was also evaluated.
机译:通过GC-MS在SCAN模式下评估了其他化合物对低浓度粪臭素和雄烯酮的脂肪样品中公猪异味发展的可能贡献。分别通过正相HPLC和GC-MS测定Skateole和雄烯酮。为了鉴定其他化合物,脂肪样品用凝胶过滤柱纯化,第二部分在室温下用KOH / 3 N MeOH皂化。 4-苯基-3-丁烯-2-酮是在脂肪样品中鉴定出的主要化合物,并且通过与从商业来源获得的标准溶液进行比较并通过HPLC证实了其鉴定。对4-苯基-3-丁烯-2-酮的感官分析表明,其对公猪异味的可能贡献。还评估了酚衍生物和短链脂肪酸的可能贡献。

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