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MALDI TOF Mass Spectrometry for the Investigation of the Structure of Ruthenium Carborane Complexes

机译:MALDI TOF质谱用于研究钌碳硼烷配合物的结构

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摘要

The results of investigation of ruthenium carborane complexes with chelating diphosphine ligands by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry are presented. The influence of matrix, power of laser irradiation, and analysis mode on the substrate fragmentation and spectra is analyzed. It is shown that the best spectra are recorded in the negative ion mode with DCTB as a matrix.
机译:给出了基质辅助激光解吸/电离飞行时间质谱研究钌与螯合二膦配体的碳硼烷配合物的结果。分析了基质,激光辐照功率和分析模式对基质碎裂和光谱的影响。结果表明,以DCTB为基质,在负离子模式下记录了最佳光谱。

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