Ni- AND Cu-CATALYZED COUPLING REACTIONS UISING 2-(4,5-DIHYDRO-1H-IMIDAZO-2-YL)PHENOL AS A VERSATILE PHOSPHINE-FREE LIGAND

Satoshi Haneda; Kazuhiko Sudo; Masahiko Hayashi

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Ni- AND Cu-CATALYZED COUPLING REACTIONS UISING 2-(4,5-DIHYDRO-1H-IMIDAZO-2-YL)PHENOL AS A VERSATILE PHOSPHINE-FREE LIGAND

机译：Ni和Cu催化的偶合无磷配体的2-（4,5-二氢-1H-咪唑-2-基）苯酚的镍和铜催化偶联反应

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We have disclosed 2-(4,5-dihydro-1H-imidazo-2-yl)phenol (1) worked efficiently as a ligand in Ni-catalyzed Suzuki-Miyaura coupling reactions and Cu-catalyzed N-cyclopropylation of indoles using cyclopropylboronic acid.

机译：我们已经公开了2-（4,5-二氢-1H-咪唑-2-基）苯酚（1）在镍催化的Suzuki-Miyaura偶联反应和铜催化的使用环丙基硼酸的吲哚的N-环丙基化反应中作为配体有效地工作。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2012年第1期|共7页
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Satoshi Haneda; Kazuhiko Sudo; Masahiko Hayashi;
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1. Ni- AND Cu-CATALYZED COUPLING REACTIONS UISING 2-(4,5-DIHYDRO-1H-IMIDAZO-2-YL)PHENOL AS A VERSATILE PHOSPHINE-FREE LIGAND [J] . Satoshi Haneda, Kazuhiko Sudo, Masahiko Hayashi Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2012,第1期

机译：Ni和Cu催化的偶合无磷配体的2-（4,5-二氢-1H-咪唑-2-基）苯酚的镍和铜催化偶联反应
2. First Application of an Efficient and Versatile Ligand for Copper-Catalyzed Cross-Coupling Reactions of Vinyl Halides with N-Heterocycles and Phenols [J] . Kabir MS, Lorenz M, Namjoshi OA, Organic letters . 2010,第3期

机译：高效，多功能的配体在卤代乙烯与N-杂环和苯酚的铜催化交叉偶联反应中的首次应用
3. 1,1,1-tris(hydroxymethyl)ethane as a new, efficient, and versatile tripod ligand for copper-catalyzed cross-coupling reactions of aryl iodides with amides, thiols, and phenols [J] . Chen YJ, Chen HH Organic letters . 2006,第24期

机译：1,1,1-三（羟甲基）乙烷是一种新型，高效且通用的三脚架配体，用于芳基碘化物与酰胺，硫醇和酚的铜催化交叉偶联反应
4. C?N and C?C Bond Forming Reaction via Cu-Catalyzed Desulfonylative Coupling Reaction [C] . Jacky C.-H. Yim, Yasuyo Tahara, Masakazu Nambo 日本化学会春季年会講演予稿集 . 2018

机译：C？N和C？C键通过Cu催化脱硫偶联反应形成反应
5. Part I: Vanadium-Catalyzed Asymmetric Oxidative Coupling of Phenols and Hydroxycarbazoles and Its Mechanistic Study. Part II: Total Synthesis of Chaetoglobin A. Part III: Ligand Evolution to Drive Reaction Discovery. Part IV: Oxidative Coupling of 3-Oxindoles to Construct Quaternary Centers [D] . Kang, Houng 2018

机译：第一部分：钒催化苯酚和羟基咔唑的不对称氧化偶合及其机理研究。第二部分：脂球蛋白A的全合成。第三部分：配体进化以驱动反应发现。第四部分：3-氧辛二烯的氧化偶联以构建四元中心
6. First Application of An Efficient and Versatile Ligand for Copper-Catalyzed Cross-Coupling Reactions of Vinyl Halides with N-Heterocycles and Phenols [O] . M. Shahjahan Kabir, Michael Lorenz, Ojas A. Namjoshi, -1

机译：对于铜催化的交叉偶联卤乙烯的反应与N-杂环酚类物质的高效率多用途配体的首次应用
7. First Application of an Efficient and Versatile Ligand for Copper-Catalyzed Cross-Coupling Reactions of Vinyl Halides with N-Heterocycles and Phenols [O] . M. Shahjahan Kabir, Michael Lorenz, Ojas A. Namjoshi, 2009

机译：首先施加高效且通用配体的铜催化的乙烯基卤化物与N-杂环和酚的交联反应
8. Phase Transfer Pd(O) Catalyzed Polymerization Reactions. 1. Synthesis of 1,2-(4,4'-Dialkoxyaryl)Acetylene Monomers and 1,4-Bis(2-(4',4''-Dialkoxyphenyl)Ethynyl)Benzene Derivatives by Phase Transfer Pd(O)/Cu(I) Catalyzed Coupling Reactions. [R] . Pugh, C., Percec, V. 1990

机译：相转移pd（O）催化的聚合反应。 1.相转移pd（O）/ Cu合成1,2-（4,4'-二烷氧基芳基）乙炔单体和1,4-双（2-（4'，4'-二烷氧基苯基）乙炔基）苯衍生物（I）催化的偶联反应。

Ni- AND Cu-CATALYZED COUPLING REACTIONS UISING 2-(4,5-DIHYDRO-1H-IMIDAZO-2-YL)PHENOL AS A VERSATILE PHOSPHINE-FREE LIGAND

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