ASYMMETRIC LEWIS ACID CATALYSIS OF ALUMINUM(SALALEN) COMPLEXES: FRIEDEL-CRAFTS REACTION OF INDOLE

Keitaro Suyaraa; Kazuhiro Matsumoto; Tsutomu Katsuki

首页> 外文期刊>Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry >ASYMMETRIC LEWIS ACID CATALYSIS OF ALUMINUM(SALALEN) COMPLEXES: FRIEDEL-CRAFTS REACTION OF INDOLE

【24h】

ASYMMETRIC LEWIS ACID CATALYSIS OF ALUMINUM(SALALEN) COMPLEXES: FRIEDEL-CRAFTS REACTION OF INDOLE

机译：铝（水杨酸）络合物的不对称路易斯酸催化：吲哚的弗里德尔-克拉夫特反应

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

团队文献服务 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

We examined the Lewis acid catalysis of chiral Al(salalen)X complexes and found that complex lb (X = Br) serves as an efficient catalyst for the Friedel-Crafts reaction of indole with N-[(E)-alkenoyl]oxazolidin-2-ones. High enantioselectivity (up to 98% ee) was obtained under the optimized conditions.

机译：我们研究了手性Al（salalen）X配合物的路易斯酸催化作用，发现配合物lb（X = Br）可作为吲哚与N-[（E）-链烯酰基]恶唑烷-2的Friedel-Crafts反应的有效催化剂-那些。在优化条件下获得了高对映选择性（高达98％ee）。

著录项

来源
《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry 》 |2009年第2期| 共8页
作者
Keitaro Suyaraa; Kazuhiro Matsumoto; Tsutomu Katsuki;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类杂环化合物 ;
关键词

相似文献

外文文献
中文文献
专利

1. ASYMMETRIC LEWIS ACID CATALYSIS OF ALUMINUM(SALALEN) COMPLEXES: FRIEDEL-CRAFTS REACTION OF INDOLE [J] . Keitaro Suyaraa, Kazuhiro Matsumoto, Tsutomu Katsuki Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2009 ,第2期

机译：铝（水杨酸）络合物的不对称路易斯酸催化：吲哚的弗里德尔-克拉夫特反应
2. Efficient Lewis acid-assisted Br?nsted acid (LBA) catalysis in the iron-catalyzed Friedel-Crafts alkylation reaction of indoles [J] . Zhen-Yu Jiang, Ji-Rong Wu, Li Li, Open Chemistry . 2010 ,第3期

机译：铁在吲哚的弗里德-克来福特烷基化反应中的高效路易斯酸辅助布朗斯台德酸（LBA）催化
3. Asymmetric carbonyl-ene and Friedel-Crafts reactions catalysed by Lewis acid platinum group metal complexes of the enantiopure atropisomeric biaryl-like diphosphine (S)-Me _2-CATPHOS: A comparison with BINAP [J] . Doherty S., Knight J.G., Mehdi-Zodeh H. Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2012 ,第3a4期

机译：对映纯阻转异构联芳基样二膦（S）-Me _2-CATPHOS的路易斯酸铂族金属配合物催化的不对称羰基烯和Friedel-Crafts反应：与BINAP的比较
4. Synthesis and Characterization of Pheox- and Phebox-Al Complexes and Its Application to the Lewis Acid Catalyzed Reactions [C] . Shuichi Nakao, Yoshihiro Nishimoto, Makoto Yasuda 日本化学会春季年会講演予稿集 . 2018

机译：嗜磷酸和浮藻硅络合物的合成与表征及其在路易斯酸催化反应中的应用
5. Studies in asymmetric catalysis: Lewis base catalyzed/Lewis acid mediated aldol reactions of ketone- and amide derived nucleophiles. [D] . Heemstra, John Richard, Jr. 2007

机译：不对称催化的研究：Lewis碱催化/路易斯酸介导的酮和酰胺衍生的亲核试剂的羟醛反应。
6. Asymmetric Friedel-Crafts Alkylation of Indole with Chalcones Catalyzed by Chiral Phosphoric Acids [O] . Arrigo Scettri, Rosaria Villano, Maria Rosaria Acocella 2009

机译：手性磷酸催化吲哚与with的不对称弗里德-克福福特烷基化反应
7. Chiral transition-metal complexes as Brønsted-acid catalysts for the asymmetric Friedel-Crafts hydroxyalkylation of indoles [O] . Carmona Daniel, Lamata M. Pilar, Sánchez Antonio, 2015

机译：手性过渡金属配合物作为Brønsted-酸催化剂用于吲哚的不对称Friedel-Crafts羟烷基化
8. Studies of hydrogen-hydrogen and carbon-sulfur bond cleavage; Lewis acid modified molybdenum sulfide complexes; and Syntheses and reactions of pyrrole complexes. Final report [R] . 1998

机译：研究氢 - 氢和碳 - 硫键裂解;路易斯酸改性硫化钼配合物;和吡咯配合物的合成和反应。总结报告

ASYMMETRIC LEWIS ACID CATALYSIS OF ALUMINUM(SALALEN) COMPLEXES: FRIEDEL-CRAFTS REACTION OF INDOLE

摘要

著录项

相似文献

相关主题

期刊订阅