SYNTHESIS OF SUNDIVERSIFOLIDE AND DIVERSIFOLIDE VIA A DIASTEREOSELECTIVE [3+2] NITRILE OXIDE CYCLOADDITION REACTION

Hiroyuki Sasaki; Hiromasa Yokoe; Mitsuru Shindo

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SYNTHESIS OF SUNDIVERSIFOLIDE AND DIVERSIFOLIDE VIA A DIASTEREOSELECTIVE [3+2] NITRILE OXIDE CYCLOADDITION REACTION

机译：非对映选择性的[3 + 2]一氧化氮环氧化物负载反应的合成

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The enantioselective synthesis of the unnatural enantiomers (-)-sundiversifolide and (+)-diversifolide has been accomplished employing a diastereoselective intramolecular [3+2] nitrile oxide cycloaddition reaction as the key step.

机译：非天然对映体（-）-sundiversifolide和（+）-diversifolide的对映选择性合成已采用非对映选择性分子内[3 + 2]腈氧化物环加成反应作为关键步骤。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2009年第2期|共5页
作者
Hiroyuki Sasaki; Hiromasa Yokoe; Mitsuru Shindo;
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中图分类杂环化合物;
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1. SYNTHESIS OF SUNDIVERSIFOLIDE AND DIVERSIFOLIDE VIA A DIASTEREOSELECTIVE [3+2] NITRILE OXIDE CYCLOADDITION REACTION [J] . Hiroyuki Sasaki, Hiromasa Yokoe, Mitsuru Shindo Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2009,第2期

机译：非对映选择性的[3 + 2]一氧化氮环氧化物负载反应的合成
2. Diastereoselective [3+2] cycloadditions of a camphor-derived chiral N-acryloylhydrazide with nitrile oxides:the preparation of optically pure #delta#~2-isoxazolines [J] . Yang Kung-Shuo, Lain Jung-Chaing, Lin Chun-Hui Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2000,第9期

机译：樟脑衍生的手性N-丙烯酰肼与腈氧化物的非对映选择性[3 + 2]环加成反应：光学纯的＃δ＃〜2-异恶唑啉的制备
3. Diastereoselective Synthesis of Cyclopentene Spiro-rhodanines Containing Three Contiguous Stereocenters via Phosphine-catalyzed [3+2] Cycloaddition or One-pot Sequential [3+2]/[3+2] Cycloaddition [J] . Zhiwei Miao, Jiayong Zhang Archives in Chemical Research . 2020,第5期

机译：异映选择性合成含有三种连续立体封闭剂的环戊烯螺葡聚糖，通过膦催化[3 + 2]环加成或单盆顺序[3 + 2] / [3 + 2]环加成
4. Catalytic Asymmetric 3+2 Cycloaddition of α-Ketoester Enolates and Nitrile Oxides [C] . Samuel Bartlett, Yoshihiro Sohtome, Daisuke Hashizume 日本化学会春季年会講演予稿集 . 2018

机译：催化不对称3 + 2环加成α-酮酯烯醇用烯醇用烯烃和腈氧化物
5. P-Stereogenic Secondary Phosphine Oxides (Spos) Derived from (+)-Limonene Oxide: Diastereoselective Synthesis, Structure, and Design of Platinum Catalyst Precursors for Asymmetric Nitrile Hydra [D] . Zimmerman, Amber N. 2020

机译：衍生自（+） - 柠檬烯氧化物的磷酸二膦氧化物（SPOS）：非对称丁腈氢化铂催化剂前体的非对映选择性合成，结构和设计
6. Unveiling the Different Chemical Reactivity of Diphenyl Nitrilimine and Phenyl Nitrile Oxide in 3+2 Cycloaddition Reactions with (R)-Carvone through the Molecular Electron Density Theory [O] . Mar Ríos-Gutiérrez, Luis R. Domingo, M’hamed Esseffar, 2020

机译：通过分子电子密度理论揭示3 + 2与（R）-香芹酮的环加成反应中二苯基硝胺和苯基氧化丁烯的不同化学反应性
7. Unveiling the Different Chemical Reactivity of Diphenyl Nitrilimine and Phenyl Nitrile Oxide in 3+2 Cycloaddition Reactions with (R)-Carvone through the Molecular Electron Density Theory [O] . Mar Ríos-Gutiérrez, Luis R. Domingo, M’hamed Esseffar, 2020

机译：通过分子电子密度理论揭示在3 + 2环加入反应中的二苯基硝基亚胺和苯基腈氧化物的不同化学反应性
8. Synthesis of Metallacycles by 1,3-Dipolar Cycloaddition Reactions Between Low-Valent Metal Carbonyls and Aryl Nitrile N-Oxides. [R] . Chetcuti, P. A., Walker, J. A., Knobler, C. B., 1988

机译：低价金属羰基化合物与芳基腈N-氧化物之间1,3-偶极环加成反应合成金属环。

SYNTHESIS OF SUNDIVERSIFOLIDE AND DIVERSIFOLIDE VIA A DIASTEREOSELECTIVE [3+2] NITRILE OXIDE CYCLOADDITION REACTION

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