PREPARATION OF IODO-INDUCED 1,3-OXATHIANE COMPOUNDS VIA INTRAMOLECULAR PUMMERER REARRANGEMENT OF 2-BENZYLSULFINYL-BICYCLO[2.2.1]HEPT-5-ENE

Abe Hitoshi; Fujii Hiroyuki

首页> 外文期刊>Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry >PREPARATION OF IODO-INDUCED 1,3-OXATHIANE COMPOUNDS VIA INTRAMOLECULAR PUMMERER REARRANGEMENT OF 2-BENZYLSULFINYL-BICYCLO[2.2.1]HEPT-5-ENE

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PREPARATION OF IODO-INDUCED 1,3-OXATHIANE COMPOUNDS VIA INTRAMOLECULAR PUMMERER REARRANGEMENT OF 2-BENZYLSULFINYL-BICYCLO[2.2.1]HEPT-5-ENE

机译：通过2-苯甲基磺酰基-双环[2.2.1] HEPT-5-ENE的分子内重整来制备碘诱导的1，3-氧杂蒽化合物

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Iodooxathianes (2a and 2b) were prepared from the #gamma#,#delat#-unsaturated sulfinyl compound (1) via the iodonium-promoted intramolecular Pummerer reaction. A two-step conversion of 1 into 2a and 2b involving iodohydrination and the Pummerer rearrangement was also achieved.

机译：通过γ-，＃delat＃-不饱和亚磺酰基化合物（1）经碘鎓促进的分子内Pummerer反应制备碘代氧杂蒽（2a和2b）。还实现了1到2a和2b的两步转化，包括碘代水合和Pummerer重排。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry 》 |2000年第1期| 共6页
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Abe Hitoshi; Fujii Hiroyuki;
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中图分类杂环化合物 ;
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1. PREPARATION OF IODO-INDUCED 1,3-OXATHIANE COMPOUNDS VIA INTRAMOLECULAR PUMMERER REARRANGEMENT OF 2-BENZYLSULFINYL-BICYCLO[2.2.1]HEPT-5-ENE [J] . Abe Hitoshi, Fujii Hiroyuki Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2000 ,第1期

机译：通过2-苯甲基磺酰基-双环[2.2.1] HEPT-5-ENE的分子内重整来制备碘诱导的1，3-氧杂蒽化合物
2. The synthesis of a 5,7-membered fused-ring compound by a tandem pummerer rearrangement and intramolecular [4+3] cycloaddition [J] . Hu YH., Bai DL., Ou LG. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1999 ,第3期

机译：通过串联pummerer重排和分子内[4 + 3]环加成反应合成5,7元稠环化合物
3. Meisenheimer and other rearrangements of n-oxides derived from 2-azabicyclo[2.2.1]hept-5-enes;the influence of reaction conditions and stereochemistry at nitrogen [J] . John R.Malpass, Paul S.Skerry, Stuart L.Rimmington Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2004 ,第1期

机译：迈森海默和2-氮杂双环[2.2.1]庚-5-烯衍生的n-氧化物的其他重排;反应条件和立体化学对氮的影响
4. Synthesis of Novel Heterotricyclic Compounds with Intramolecular 1,3- Dipolar Cycloaddition [C] . Cong Wang International symposium for Chinese organic chemists . 2000

机译：用分子内1,3-偶极环加入合成新型异质循环化合物
5. Addition of H-phosphonates to quinine-derived carbonyl compounds. An unexpected C9 phosphonate–phosphate rearrangement and tandem intramolecular piperidine elimination [O] . Łukasz Górecki, Artur Mucha, Paweł Kafarski 2014

机译：将H-膦酸酯加到奎宁衍生的羰基化合物上。意外的C9膦酸酯-磷酸重排和串联的分子内哌啶消除
6. I. Gas-phase intramolecular Diels-Alder reactions of 2,3-dimethylene-2,3-dihydrofurans; II. Formation of anthracene and other polycyclic aromatic compounds in the pyrolysis of 1,5-dibenzocyclooctadienes and related compounds; III. Formation of 9-methylanthracene and anthracene in the pyrolysis of 5,6,11,12-tetrahydrodibenzo[a,e]cyclooctene and other related compounds; IV. Preparation of cyclopentadienones by flash vacuum pyrolysis and their dimerization and intramolecular reactions [O] . Lee, Suk Kyu 1987

机译：I.2，3-二亚甲基-2，3-二氢呋喃的气相分子内Diels-Alder反应；二。 1,5-二苯并环辛二烯及相关化合物的热解过程中形成蒽和其他多环芳族化合物；三，在5,6,11,12-四氢二苯并[a，e]环辛烯和其他相关化合物的热解中形成9-甲基蒽和蒽； IV。闪蒸热解法制备环戊二烯酮及其二聚化和分子内反应

PREPARATION OF IODO-INDUCED 1,3-OXATHIANE COMPOUNDS VIA INTRAMOLECULAR PUMMERER REARRANGEMENT OF 2-BENZYLSULFINYL-BICYCLO[2.2.1]HEPT-5-ENE

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