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A simple preparative method of N-arylindigos and substitution effect in UV/visible absorption

机译:N-芳基靛蓝的简单制备方法和紫外/可见光吸收中的取代作用

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摘要

N-Aryl- and N,N'-diarylindigos were prepared by refluxing corresponding aryl iodides or bromide with indigo in o-dichlorobenzene. Variation of their UV/visible spectra with the ring-substitution was discussed on the basis of the captodative and steric effects.
机译:N-芳基-和N,N'-二芳基靛蓝是通过将相应的芳基碘化物或溴化物与靛蓝在邻二氯苯中回流制备的。讨论了它们的紫外/可见光谱随环取代作用的变化,并基于俘获性和空间位阻效应。

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