REACTIONS OF BIS(SILYL-SUBSTITUTED) METHYLLITHIUM WITH alpha-HYDROGEN-FREE NITRILES INTO 1,3,5-TRIAZINES

Xia Chen; Sheng-Di Bai; Li Wang; Dian-Sheng Liu

首页> 外文期刊>Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry >REACTIONS OF BIS(SILYL-SUBSTITUTED) METHYLLITHIUM WITH alpha-HYDROGEN-FREE NITRILES INTO 1,3,5-TRIAZINES

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REACTIONS OF BIS(SILYL-SUBSTITUTED) METHYLLITHIUM WITH alpha-HYDROGEN-FREE NITRILES INTO 1,3,5-TRIAZINES

机译：双（甲硅烷基）甲硅烷基与无α-氢的腈反应成1,3,5-三嗪

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摘要

Bis(silyl-substituted) methyllithium has been found to catalyze a conversion of a-hydrogen-free nitriles directly to yield 2,4,6-trisubsituted s-triazines.The generally high yields and relatively mild reaction conditions of this procedure suggest an alternative to other aromatic nitrile cyclotrimerization reactions.Silicotropic rearrangements from C to N or N to N and an unusual elimination of LiCR_2R (R=SiMe_3,R=SiMe_2NMe_2) were observed.

机译：已发现双（甲硅烷基取代的）甲基锂可催化无氢的腈直接转化为2,4,6-三取代的s-三嗪。观察到从C到N或N到N的硅原子重排以及LiCR_2R的异常消除（R = SiMe_3，R = SiMe_2NMe_2）。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2005年第6期|共6页
作者
Xia Chen; Sheng-Di Bai; Li Wang; Dian-Sheng Liu;
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1. REACTIONS OF BIS(SILYL-SUBSTITUTED) METHYLLITHIUM WITH alpha-HYDROGEN-FREE NITRILES INTO 1,3,5-TRIAZINES [J] . Xia Chen, Sheng-Di Bai, Li Wang, Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2005,第6期

机译：双（甲硅烷基）甲硅烷基与无α-氢的腈反应成1,3,5-三嗪
2. Reactions of chlorocarbonyl isocyanate with 5-aminopyrazoles and active methylene nitriles: A Novel synthesis of pyrazolo[1,5-a]-1,3,5-triazines and barbiturates [J] . Galal H.Elgemeie, Samia R.El-Ezbawy, Hany A.Ali Synthetic Communications . 2001,第22期

机译：氯羰基异氰酸酯与5-氨基吡唑和活性亚甲基的反应：吡唑并[1,5-a] -1,3,5-三嗪和巴比妥酸酯的新型合成
3. Mechanistic studies of the reaction of bis(2,4,6-tripyridyl 1,3,5-triazine)iron(II) with triazines [J] . Nageswara Rao Anipindi Transition Metal Chemistry . 2012,第4期

机译：双（2,4,6-三吡啶基1,3,5-三嗪）铁（II）与三嗪反应的机理研究
4. Novel bis-trinitromethylation-alkoxylation reaction of 2,4,6-trichloro-1,3,5-triazine [C] . Alexander A. Gidaspov, Vladimir V. Bakharev, Vladimir A. Zalomlenkov, Seminar on New Trends in Research of Energetic Materials . 2013

机译：2,4,6-三氯-1,3,5-三嗪的新型双三硝基甲基化-烷氧基化反应
5. Computational Investigation of the α-γ Phase Transformation in 1,3,5-trinitroperhydro-1,3,5- Triazine [D] . Josyula, Kartik 2018

机译：1,3,5-三硝基过氢-1,3,5-三嗪中α-γ相变的计算研究
6. Cannabinoid Receptor 2 Signalling Bias Elicited by 2,4,6-Trisubstituted 1,3,5-Triazines [O] . Caitlin R. M. Oyagawa, Sara M. de la Harpe, Yurii Saroz, 2018

机译：2,4,6-三取代的1,3,5-三嗪引发的大麻受体2信号偏向
7. The Reaction of Nitriles under High Pressure. IV. The Replacement of the Substituents of Trialkyl-1,3,5-triazines [O] . Koshin Yanagiya, Masahiko Yasumoto, Masahiro Kurabayashi 1973

机译：腈在高压下的反应。 IV。替代三烷基-1,3,5-三嗪的取代基
8. Formation of the Protonated Dimer of Hexahydro-1,3,5-trinitro-1,3,5-triazine by Complex Switching Reactions [R] . Doyle, R. J., Campana, J. E., Eyler, J. R. 1985

机译：通过复合开关反应形成六氢-1,3,5-三硝基-1,3,5-三嗪的质子化二聚体

REACTIONS OF BIS(SILYL-SUBSTITUTED) METHYLLITHIUM WITH alpha-HYDROGEN-FREE NITRILES INTO 1,3,5-TRIAZINES

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