Copper(II)Organic Compounds as Intermediates of Photochemical Transformations of Quaternary Ammonium Tetrachlorocuprates

摘要

Stable organometallic compounds with a Cu(II)-C sigma bond have not been described[1].Pulse radiolysis and photolysis of divalent copper salts in aqueous solutions[2,3]and in n-donor solvents[4]gave short-lived copper complexes with organic radicals in which the copper oxidation state was presumably two.Dissociation[2]