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Abnormal Intermetallic Compound formation of Cold Sprayed Cu-Sn coatings

机译:冷喷涂Cu-Sn涂层的金属间化合物异常形成

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摘要

Cu-Sn composites coatings by cold spray with wide ranges of particle size and shape (round to flake) were investigated regarding their intermetallic compound (IMC) formation. It was found when certain size and shape combination of Cu-Sn composite raw materials were employed, the embedded Cu-Sn IMCs such as Cu_6Sn_5 and Cu_3Sn were observed even in assprayed states without additional heat treatments. These results implied that the impact energy of colliding particles of the cold spraying could be enough to activate IMC compounding process. It seems that this can be also true in several composite systems that have relatively low activation energy of IMC compounding. After post annealing, the Cu_6Sn_5 formed in as-coated state were transformed into the Cu_3Sn phase and the residue of unreacted Sn particles were fully changed into the Cu_3Sn phase (Cu_6Sn_5→Cu_3Sn). These conversion processes also depended strongly on the choices of the shape and size combinations of Cu and Sn particles.
机译:研究了通过冷喷涂制备的具有宽范围粒径和形状(从圆形到片状)的Cu-Sn复合材料涂层的金属间化合物(IMC)的形成。发现当使用一定尺寸和形状的Cu-Sn复合原料组合时,即使在喷涂状态下也无需进行额外的热处理,也可以观察到嵌入的Cu-Sn IMC,例如Cu_6Sn_5和Cu_3Sn。这些结果表明,冷喷涂碰撞颗粒的冲击能足以激活IMC复合过程。似乎在IMC配混的活化能相对较低的几种复合系统中,这也是正确的。后退火后,以涂覆状态形成的Cu_6Sn_5转变为Cu_3Sn相,未反应的Sn颗粒残留物完全转变为Cu_3Sn相(Cu_6Sn_5→Cu_3Sn)。这些转化过程也强烈取决于Cu和Sn颗粒的形状和尺寸组合的选择。

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