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Experimental Corroboration of the Synthesis of Diamond in the Cavitation Process

机译:空化过程中金刚石合成的实验验证

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Thirty years ago, one of us (E.M.G.) theoretically justified the possibility of synthesizing diamonds in a cavitating fast fluid flow [1]. In that and more recent works [2, 3], variants of the cavitation synthesis of diamonds in nature were discussed. The essence of the idea is as follows. When a fluid rises rapidly from the mantle to the ground through a narrow channel–crack formed by it, sharp pressure differences arise. According to the Bernoulli equation, pressure in the fluid flow is inversely proportional to the velocity squared. Therefore, pressure decreases in a narrow spot, which givesrise to the appearance of gas bubbles. When the fluid again enters a wide place, pressure is recovered and bubbles collapse. Calculation shows that pressure can increase by several orders of magnitude. As was calculated in [1], pressure induced when bubbles filled with a carbon-containing gas collapse is sufficient for diamond synthesis. In [1, 2], it was assumed that the fluid contained CO_2, but a more recent analysis of diffusion velocities from the collapse medium showed that only hydrogen has a sufficiently high diffusion velocity. Therefore, a hydrocarbon substrate such as methane must be the initial substance.
机译:三十年前,我们中的一个人(E.M.G.)从理论上证明了在空化快速流体流动中合成钻石的可能性[1]。在那篇以及最近的著作中[2,3],讨论了自然界中钻石空化合成的变体。这个想法的实质如下。当流体通过地幔形成的狭窄通道裂缝从地幔迅速上升到地面时,就会出现急剧的压力差。根据伯努利方程,流体流动中的压力与速度平方成反比。因此,压力在狭窄的地方减小,这引起气泡的出现。当流体再次进入较宽的地方时,压力恢复并且气泡破裂。计算表明压力可以增加几个数量级。如[1]中所计算,当填充有含碳气体的气泡破裂时所产生的压力足以进行金刚石合成。在[1,2]中,假设流体中含有CO_2,但是最近对崩塌介质中扩散速度的分析表明,只有氢才具有足够高的扩散速度。因此,碳氢化合物底物(例如甲烷)必须是初始物质。

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