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La coupe du roi and other methods to halve objects

机译:La coupe du roi和其他将物件减半的方法

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The symmetry theory of halving objects into two identical fragments is developed and illustrated by examples. La coupe du roi is a fascinating way to slice an apple into chiral fragments with the same handedness. It may be applied to any object with point group symmetry 2 or 222 and their supergroups, e.g. to cones, cylinders or spheres. Variants of coupes du roi are presented and applied to a cube. An object is divided into halves by a number of cuts. The important cuts extend to the centre of the object, and these must form a single closed loop. The symmetry of the division into two fragments is given by the point group of the decorated object, i.e. the object including all the cuts. Point groups comprising only rotations result in chiral fragments with the same handedness. Such divisions may illustrate the reaction path for changing the sense of chirality of molecules via a dimeric achiral transition state rather than by deformation. Non-trivial divisions of objects into achiral fragments or into racemic chiral fragments are obtained with point groups, again of the decorated object, comprising roto-inversions (X) over bar, excepting X = 4n + 2. All other point groups either do not lead to half-objects, or they result in a trivial single planar cut parallel to a mirror plane.
机译:将对象分成两个相同的片段的对称理论得到发展,并通过示例进行了说明。 La coupe du roi是一种将苹果切成相同手性的有趣方法。它可以应用于点组对称性为2或222的任何对象及其超组,例如:到圆锥体,圆柱体或球体。提出了政变的变种并将其应用于立方体。一个对象通过多次切割被分为两半。重要的切口延伸到对象的中心,并且这些切口必须形成单个闭环。分为两个片段的对称性由装饰对象的点组给出,即包含所有切口的对象。仅包含旋转的点组会产生具有相同旋手性的手性片段。这种划分可以说明通过二聚手性过渡态而不是通过变形来改变分子的手性感的反应路径。使用点组再次将对象非平凡地分为非手性片段或外消旋手性片段,该点对象又是修饰对象,包括在bar上的旋转反转(X),但X = 4n + 2除外。所有其他点组都不导致半物体,或者它们导致平行于镜平面的琐碎的单个平面切割。

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