Photo-activation of Pd-catalyzed Sonogashira coupling using a Ru/bipyridine complex as energy transfer agent

Osawa M; Nagai H; Akita M

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Photo-activation of Pd-catalyzed Sonogashira coupling using a Ru/bipyridine complex as energy transfer agent

机译：钌/联吡啶配合物作为能量转移剂对钯催化的Sonogashira偶联的光活化

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摘要

The mixed catalyst system, Pd(CH3CN)(2)Cl-2/P(t-Bu)(2)/[Ru(2, 2'-bipyridine)(3)](.)2PF(6), promotes the copper-free Sonogashira coupling reaction of aryl bromides at room temperature under irradiation of visible light.

机译：混合催化剂体系Pd（CH3CN）（2）Cl-2 / P（t-Bu）（2）/ [Ru（2，2'-联吡啶）（3）]（。）2PF（6）促进了室温下在可见光照射下，芳基溴化物的无铜Sonogashira偶联反应。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第8期|共3页
作者
Osawa M; Nagai H; Akita M;
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正文语种 eng
中图分类无机化学;
关键词
COPPER-FREE; TERMINAL ALKYNES; ROOM-TEMPERATURE; VISIBLE-LIGHT; ARYL BROMIDES; POLYPYRIDINE COMPLEXES; AEROBIC CONDITIONS; EFFICIENT; WATER; ELECTROCHEMISTRY;

机译：无铜;末端烷基;室温;可见光;芳族溴化物;聚吡啶络合物;好氧条件;高效;水;电化学;

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1. Photo-activation of Pd-catalyzed Sonogashira coupling using a Ru/bipyridine complex as energy transfer agent [J] . Osawa M, Nagai H, Akita M Dalton transactions: An international journal of inorganic chemistry . 2007,第8期

机译：钌/联吡啶配合物作为能量转移剂对钯催化的Sonogashira偶联的光活化
2. Efficient Energy Transfer and Metal Coupling in Cyanide-Bridged Heterodinuclear Complexes Based on (Bipyridine)(terpyridine)ruthenium(II) and (Phenylpyridine)iridium(III) Complexes [J] . Barthelmes Kevin, Jaeger Michael, Kuebel Joachim, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2016,第11期

机译：（联吡啶）（三联吡啶）钌（II）和（联吡啶）铱（III）络合物在氰化物桥联的异核复合物中的高效能量转移和金属耦合
3. Sensitive immunosensor based on high effective resonance energy transfer of lucigenin to the cathodic electrochemiluminescence of tris(bipyridine) Ru(II) complex [J] . Biosensors & Bioelectronics: The International Journal for the Professional Involved with Research, Technology and Applications of Biosensers and Related Devices . 2020,第期

机译：基于高效共振能量转移的鳞茎敏感的免疫传感器TRIS（二吡啶）Ru（II）复合物的阴茎电化学荧光
4. Photoluminescence properties and comparative analysis of the new compound of Zn(II) with piridoxalaminoguanidine and Ru(II) bipyridine complex [C] . Jelic M.G., Radanovic M.M., Romcevic N.Z., 2014 29th International Conference on Microelectronics Proceedings . 2014

机译：新的Zn（II）与吡al草氨基胍和Ru（II）联吡啶配合物的光致发光性质及比较分析
5. Spectroscopic and Electrochemical Studies of [Ru(1,10-phenanthroline) 2(4,4'- dihydroxy-2,2'-bipyridine)]2+ and Related Complexes. [D] . Kuhn, Ashley E. 2017

机译：[Ru（1,10-phenothroline）2（4,4'-dihydroxy-2,2'-bipyridine）] 2+及其相关配合物的光谱和电化学研究。
6. ppm Pd-catalyzed Cu-free Sonogashira couplings in water using commercially available catalyst precursors [O] . Bo Jin, Fabrice Gallou, John Reilly, 2019

机译：使用市售催化剂前体在水中ppm钯催化的无铜Sonogashira偶联
7. ppm Pd-catalyzed, Cu-free Sonogashira couplings in water using commercially available catalyst precursors [O] . Bo Jin, Fabrice Gallou, John Reilly, 2019

机译：PPM PD催化，使用市售的催化剂前体在水中的无CU的Sonogashira联轴器
8. Solvent Dependence of Metal-to-Ligand Charge-Transfer Transitions. Evidence for Initial Electron Localization in MLCT Excited States of 2,2'-Bipyridine Complexes of Ru(II) And Os(II) [R] . Kober, E. M., Sullivan, B. P., Meyer, T. J. 1983

机译：金属与配体电荷转移跃迁的溶剂依赖性。 Ru（II）和Os（II）2,2'-联吡啶配合物mLCT激发态初始电子定位的证据

Photo-activation of Pd-catalyzed Sonogashira coupling using a Ru/bipyridine complex as energy transfer agent

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