Synthesis,crystal structure and optical properties of[Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2]:A novel compound containing closed-shell 3d~(10),4d~(10)and 5d~(10)metal ions

摘要

[Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2](1,OAc=CH3-COO)crystallized from an ethanol solution and its structure was determined by IR spectroscopy,elemental analysis,~1H NMR,~(13)C NMR and X-ray crystallography;it is composed of[Zn(H2O)4(CH3CH2OH)2]~(2+)cations and[Ag(UO2)~(3-)(OAc)9]~(2-)anions in which triuranyl[(UO2)(OAc)3]3 clusters are linked by the Ag ion.