A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO _2 adsorption

Mowat J.P.S.; Seymour V.R.; Griffin J.M.; Thompson S.P.; Slawin A.M.Z.; Fairen-Jimenez D.; Düren T.; Ashbrook S.E.; Wright P.A.

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A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO _2 adsorption

机译：-类似物的一种新型MIL-53结构形式及其对温度变化和CO _2吸附的响应

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The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO _2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO _2.

机译：柔性对苯二甲酸酯MIL-53的analogue类似物在去除客体分子后会产生新颖的封闭孔结构，该结构具有异常的热行为和在CO _2吸附过程中逐步打开。相比之下，硝基官能化的MIL-53（Sc）不能完全闭合，并且该结构具有永久的CO _2孔隙率。

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《Dalton transactions: An international journal of inorganic chemistry 》 |2012年第14期| 共5页
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Mowat J.P.S.; Seymour V.R.; Griffin J.M.; Thompson S.P.; Slawin A.M.Z.; Fairen-Jimenez D.; Düren T.; Ashbrook S.E.; Wright P.A.;
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1. A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO _2 adsorption [J] . Mowat J.P.S., Seymour V.R., Griffin J.M., Dalton transactions: An international journal of inorganic chemistry . 2012 ,第14期

机译：-类似物的一种新型MIL-53结构形式及其对温度变化和CO _2吸附的响应
2. Adsorption Forms of CO2 on MIL-53(Al) and MIL-53(Al) OHx As Revealed by FTIR Spectroscopy [J] . Andonova Stanislava, Ivanova Elena, Yang Jie, The journal of physical chemistry, C. Nanomaterials and interfaces . 2017 ,第34期

机译：FTIR光谱透露的MIL-53（Al）和MIL-53（Al）OHX上的CO2的吸附形式
3. Molecular Dynamics Simulations of Breathing MOFs: Structural Transformations of MIL-53(Cr) upon Thermal Activation and CO2 Adsorption [J] . Fabrice Salles, Aziz Ghoufi, Guillaume Maurin Angewandte Chemie . 2008 ,第44期

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机译：基于工作温度的变化和主要初始浓度的变化，使用金属 - 有机框架HKUST-1分析锶等温吸附
5. Corrosion, microstructural and mechanical characteristics of advanced aluminum-magnesium alloys with scandium and zirconium additions at elevated temperatures. [D] . Abbas, Mohammed. 2005

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A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO _2 adsorption

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