The generation of a novel polyoxometalate-based 3D framework following picolinate-chelation of tungsten and potassium centres

Ritchie C.; Miller C.E.; Boskovic C.

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The generation of a novel polyoxometalate-based 3D framework following picolinate-chelation of tungsten and potassium centres

机译：钨和钾中心的吡啶甲酸螯合后，生成基于多金属氧酸盐的新型3D框架

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A new polyoxometalate-based 3D framework K_5Na[K _2{Dy(H_2O)_3}_2{As_2W _(19)O_(68)}{WO_2(pic)}_2] (1) (pic = 2-picolinate), composed of picolinate-functionalised dysprosium-containing tungstoarsenates and distorted potassium-picolinate cubane units, has been synthesised from the polyoxometalate precursor [As_2W _(19)O_(67)(H_2O)]~(14-).

机译：一个新的基于多金属氧酸盐的3D框架K_5Na [K _2 {Dy（H_2O）_3} _2 {As_2W _（19）O_（68）} {WO_2（pic）} _ 2]（1）（pic = 2-picolinate）组成多金属氧酸盐前体[As_2W _（19）O_（67）（H_2O）]〜（14-）合成了吡啶甲酸官能化的含钨钨酸盐和扭曲的吡啶甲酸钾古巴仑单元。

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《Dalton transactions: An international journal of inorganic chemistry》 |2011年第45期|共3页
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Ritchie C.; Miller C.E.; Boskovic C.;
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1. The generation of a novel polyoxometalate-based 3D framework following picolinate-chelation of tungsten and potassium centres [J] . Ritchie C., Miller C.E., Boskovic C. Dalton transactions: An international journal of inorganic chemistry . 2011,第45期

机译：钨和钾中心的吡啶甲酸螯合后，生成基于多金属氧酸盐的新型3D框架
2. A novel organic-inorganic hybrid polyoxometalate-based 3D framework constructed by organo-functionalized [As2W21O72(mal)(2)](18-) units and Ce3+ ions [J] . Ma Pengtao, Wang Yangyang, Si Yanan, Inorganic Chemistry Communications . 2017,第期

机译：由有机官能化[As2W21O72（MAL）（2）]（18-）单位和CE3 +离子构成的基于基于基于基于基于的基于杂种聚氧膦酸酯的3D框架
3. Two 3D Polyoxometalate-based Frameworks Constructed from Silver(I) triazole/tetrazole Units: Hydrothermal Syntheses, Crystal Structure and Properties [J] . Tian Ai-Xiang, Hou Xue, Ying Jun, Zeitschrift fur Anorganische und Allgemeine Chemie . 2015,第15期

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4. Deep oxidative desulfurization of dibenzothiophene by functional tungsten-containing mesoporoussilica from polyoxometalate-based salts [C] . Ming Zhang, Wenshuai Zhu, Meng Li International Conference on Molecular Imprinting . 2015

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The generation of a novel polyoxometalate-based 3D framework following picolinate-chelation of tungsten and potassium centres

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