Synthesis and characterization of IPrMe-containing silver(I), gold(I) and gold(III) complexes

摘要

The compounds 4,5-dimethyl-N, N'-bis(2,6-diisopropylphenyl) imidazol-2-ylidene silver chloride [AgCl(IPrMe)] 3 and 4,5-dimethyl-N, N'-bis(2,6-diisopropylphenyl) imidazol-2-ylidene gold(I) chloride [AuCl(IPrMe)] 4 have been synthesized. The attempted synthesis of the corresponding 4,5-dimethyl-N, N'-bis(2,6-diisopropylphenyl) imidazol-2-ylidene gold(III) chloride by oxidative addition of chlorine gas on 4 allowed for the formation of the expected complex, concomitantly with 6, resulting from a chlorination of a methyl group situated in the backbone of the NHC (N-heterocyclic carbene). Additionally, the buried volume %V-bur of the IPrMe ligand in [AgCl(IPrMe)] 3 and [AuCl(IPrMe)] 4 complexes was calculated and compared to %V-bur of more classical NHCs. This quanti. cation of the steric hinderance of the IPrMe ligand reveals the influence of the substituent modulation in the backbone of NHCs.