Synthesis and Structural Characterization of a New Two-dimensional Organic-Inorganic Hybrid Molybdoarsenate: [Cu(en)_2]_2[(CuO_6)Mo_6O_(18)(As_3O_3)_2]

Qiang Wu; Qiuxia Han; Lijun Chen; Pengtao Ma; Jingyang Niu

首页> 外文期刊>Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences >Synthesis and Structural Characterization of a New Two-dimensional Organic-Inorganic Hybrid Molybdoarsenate: [Cu(en)_2]_2[(CuO_6)Mo_6O_(18)(As_3O_3)_2]

【24h】

Synthesis and Structural Characterization of a New Two-dimensional Organic-Inorganic Hybrid Molybdoarsenate: [Cu(en)_2]_2[(CuO_6)Mo_6O_(18)(As_3O_3)_2]

机译：新型二维有机-无机杂化钼酸镧[Cu（en）_2] _2 [（CuO_6）Mo_6O_（18）（As_3O_3）_2]的合成及结构表征

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A new organic-inorganic hybrid molybdoarsenate constructed from a unit with two (As303) rings capping Anderson-type moieties, [Cu(en)_2]_2[(CuO_6)Mo_6O_(18)(As_3O_3)_2] (1) (en = ethylenediamine), has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction and thermogravimetric analysis. The compound crystallizes monoclinically, space group P2_1/c, with unit cell dimensions a= 9.1541(7), b = 19.6348(14), c = 14.5205(8) A, β = 129.082(3)°, V = 364.20(4) A~3, Z = 2, T = 296(2) K. Complex 1 represents the first example of a 2D network of a POM polymer where [(CuO_6)Mo_6O_(18)(As_3O_3)_2]~(4-) building blocks are connected by complex fragments {Cu(en)_2}~(2+).

机译：一种新的有机-无机杂化钼酸砷酸盐，由具有两个（As303）环加盖安德森型部分[Cu（en）_2] _2 [（CuO_6）Mo_6O_（18）（As_3O_3）_2]（1）的单元构成乙二胺），已经水热合成，并通过单晶X射线衍射和热重分析进行了表征。该化合物单晶结晶，空间群P2_1 / c，晶胞尺寸a = 9.1541（7），b = 19.6348（14），c = 14.5205（8）A，β= 129.082（3）°，V = 364.20（4 ）A〜3，Z = 2，T = 296（2）K。配合物1代表POM聚合物2D网络的第一个例子，其中[（CuO_6）Mo_6O_（18）（As_3O_3）_2]〜（4-）构建块通过复杂的片段{Cu（en）_2}〜（2+）连接。

著录项

来源
《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2010年第2期|共5页
作者
Qiang Wu; Qiuxia Han; Lijun Chen; Pengtao Ma; Jingyang Niu;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Polyoxometalate; Hydrothermal Synthesis; Crystal Structure; Anderson-type Unit;

机译：多金属氧酸盐;水热合成;晶体结构;安德森型单元;

相似文献

外文文献
中文文献
专利

1. Synthesis and Structural Characterization of a New Two-dimensional Organic-Inorganic Hybrid Molybdoarsenate: [Cu(en)_2]_2[(CuO_6)Mo_6O_(18)(As_3O_3)_2] [J] . Qiang Wu, Qiuxia Han, Lijun Chen, Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2010,第2期

机译：新型二维有机-无机杂化钼酸镧[Cu（en）_2] _2 [（CuO_6）Mo_6O_（18）（As_3O_3）_2]的合成及结构表征
2. Synthesis, structural investigation and characterization of an α-keggin-based organic-inorganic hybrid, [Cu(BIIM)~2]{[Cu(BIIM) ~2(H2O)][Cu(BIIM)~2BW1~2O ~(40)]·3H2O}~2 (BIIM = 2,2'-Biimidazole) [J] . Wei L.-H., Wang Z.-L., Li M.-X. Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2013,第11期

机译：α-角蛋白基有机-无机杂化体[Cu（BIIM）〜2] {[Cu（BIIM）〜2（H2O）] [Cu（BIIM）〜2BW1〜2O〜（40）的合成，结构研究和表征）]·3H2O}〜2（BIIM = 2,2'-苯并咪唑）
3. Hydrothermal synthesis and structural characterization of prototypical organic-inorganic hybrid materials: [{Cu(2,2 '-bpy)-(H2O)}(VO)(O3PCH2PO3)], [Cu(2,2 '-bpy)(VO)(O3PCH2CH2PO3)], and [Cu(2,2 '-bpy)(VO)(O3PCH2CH2CH2PO3)]center dot H2O. Bimetallic p [J] . Finn RC., Zubieta J. Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2000,第12期

机译：典型的有机-无机杂化材料的水热合成和结构表征：[{Cu（2,2'-bpy）-（H2O）}（VO）（O3PCH2PO3）]，[Cu（2,2'-bpy）（VO）（O3PCH2CH2PO3）]和[Cu（2,2'-bpy）（VO）（O3PCH2CH2CH2PO3）]中心点H2O。双金属p
4. Synthesis and Structural Characterization of a Novel Two-Dimensional Cluster Polymer{Me4N2MoOS3Cu3(μ2-I)3 }n [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：新型二维团簇聚合物{Me4N 2 MoOS3Cu3（μ2-I）3} n的合成与结构表征
5. Synthesis of organic-inorganic hybrids via ozone chemistry: Synthesis, characterization and mechanical properties of polystyrene-polyetherimide ABA block copolymers. [D] . Karandinos, Anthony George. 1997

机译：通过臭氧化学合成有机-无机杂化物：聚苯乙烯-聚醚酰亚胺ABA嵌段共聚物的合成，表征和力学性能。
6. Microstructural Study of Two-Dimensional Organic-Inorganic Hybrid Perovskite Nanosheet Degradation under Illumination [O] . Lingfang Nie, Xiaoxing Ke, Manling Sui 2019

机译：照明下二维有机-无机杂化钙钛矿纳米片降解的微观结构研究
7. Synthesis and Structural Characterization of a New Two-Dimensional Polymeric Hybrid Material {CuSUB3/SUB(iμ/iSUB3/SUB-1,2,3-BTC)(iμ/iSUB2/SUB-1,2,3-BTC)(en)SUB3/SUB(OHSUB2/SUB)SUB2/SUB(OH)(iμ/iSUB2/SUB-OHSUB2/SUB)SUB2/SUB#183;5HSUB2/SUBO#183;O}SUBn/SUB [O] . Alvine L. Djoumbissie, Francis W. Njifack, Alain T. Djampouo, 2020

机译：新型二维聚合物杂交材料的合成和结构表征{Cu _{3 （μ-/ i> _{3 -1,2,3-btc）（μ _{2 -1,2,3-btc）（en）_{3 （OH _{2 ）_{2 （OH）（μl> _{2 -OH _{2 ） _{2 ·5h _{2 O·O} _n}}}}}}}}}}
8. Synthesis of the Two Epimeric 6-Carbomethoxy-1,5-Dimethyl-endo-tricyclo(5.2.1.0(2,6))dec-8-en-3-0nes. Unequivocal Structural Assignment of the 5-Alpha-and 5Beta-Isomers via Two-Dimensional NMR Spectroscopy [R] . Smith, W. B., Marchand, A. P., Suri, S. C., 1986

机译：合成两个差向异构体-6-甲氧基-1,5-二甲基 - 内 - 三环（5.2.1.0（2,6））癸-8-烯-3-0nes。通过二维NmR光谱法对5-α和5Beta-异构体进行明确的结构分配

Synthesis and Structural Characterization of a New Two-dimensional Organic-Inorganic Hybrid Molybdoarsenate: [Cu(en)_2]_2[(CuO_6)Mo_6O_(18)(As_3O_3)_2]

摘要

著录项

相似文献

相关主题

期刊订阅