Electrodeposition and corrosion resistance of Zn-Pd alloy from the ZnCl2-EMIC(1-ethyl-3-methylimidazolium chloride)-PdCl2 room temperature molten salt

摘要

Electric conductivities of 50-50 mol% ZnCl2-EMIC and its mixtures with 0.6714 mol% PdCl2 room-temperature molten salts (RTMS) have been measured by a computerized system based on a d.c. four-probe method. The conductivity of the former is greater than that of the latter. These conductivities are well fitted by Arrhenius equations and the activation energies are calculated to be 25.22 and 26.28 KJ/mol, respectively. Cyclic voltammetry for the ZnCl2-EMIC-PdCl2 melt has been performed on Pt and Cu working electrodes. The cathodic reduction waves of Pd2+ and Zn2+ species and the oxidation waves for Zn-Pd alloys rich in Zn and I'd have been observed for the cyclic voltammograms on the Pt working electrode. The deposition potentials have been measured to be -0.7 V and -1.3 V on the Cu substrate. The morphology and composition of the electrodeposited layers obtained under different conditions have been analyzed by SEM and EDS, respectively; layers with a finer (about 300 - 500 nm), denser and higher Pd content have been obtained by pulse plating on the Cu sheet at t(on)/t(off) 3/1 under -0.7 V at 80 degreesC. The XRD patterns also reveal that the structure of these deposited layers can be regarded as amorphous. Tafel polarization curves of the electrodeposited layers in 3.5 wt% NaCl solution have been drawn. The results indicate that the Zn-Pd alloy deposits have much higher corrosion resistance and protection efficiency than the Zn-deposited layer; the corrosion potentials shift positively by about 700 similar to 950 mV. Furthermore, the pulse plating has a better performance than the direct current plating, and the reason is discussed. [References: 27]