Precise Pb isotope ratio determination of picogram-size samples: A comparison between multiple Faraday collectors equipped with 10(12) Omega amplifiers and multiple ion counters

摘要

While typical ion-counting peak hopping methods using a single Daly detector or a single secondary electron multiplier have proven very effective in analyzing small Pb samples by TIMS, the measurements often require long acquisition times, typically of several hours. Here we compare and evaluate static multi-collector determination of Pb isotope ratios in samples containing between 100 and 1 pg total Pb using Faraday detectors, equipped with 10(12) Omega feedback resistors in the current amplifier system, versus a multiple ion counting (MIC) system, installed in a Triton Plus TIMS. Faraday cup measurements of pg size Pb samples using 10(12) Omega amplifiers require precise measurement of long baselines for optimal repeatability (defined as internal precision or the precision of a single run) and intermediate precision (defined as the closeness of the replicated measurements over an extended period of time). In our system, using a 20 min baseline before and after the measurement, we achieved a repeatability of 0.02-0.03% (2SE) and an intermediate precision of 0.05% (2SD) on Pb-207/Pb-206 and Pb-208/Pb-206 in as little as 1 h for samples containing between 80 and 10 pg Pb. This is equivalent to the performance obtained from a 4 to 5 hour-long single SEM peak hopping analysis of larger (10.0-0.5 ng) samples. For measurements in MIC mode, the main analytical uncertainty is the relative instability of the detector yields, which is 0.1-0.3% (2SD; following a 1 hour detector stabilization period). Using a correction based on the average yield measured before and after sample analysis, we achieved a repeatability of 0.03%-0.06% (2SE) and an intermediate precision of 0.18%-0.23% (2SD) on Pb-207/Pb-206 for 80 to 10 pg loads. For sample sizes between 10 and 1 pg, which were only measured in MIC mode because the Pb-204 intensity is below detection limit in Faraday mode, the main source of uncertainty is the variable loading blank contribution (5-15%). We conclude that a Faraday array equipped with 10(12) Omega amplifiers performs very well for Pb sample load sizes down to 10 pg, allowing much more rapid data acquisition than peak-hoping SEM measurements and producing data that is 4-5 times more precise than static MIC measurements. In contrast, the MIC system offers considerable promise for tracer Pb work in the sub-10 pg Pb analyte range where data with a few % level of accuracy and precision are useful, providing that acceptable total procedural blanks (below 0.1 pg) can be achieved. (C) 2014 Elsevier B. V. All rights reserved.