Synthesis and spectroscopic characterization of the heterosilylated anions [PW9O34((BuSiO)-Bu-t)(3)(SiR)](3-) (R = -CH3, -CH=CH2, -CH2-CH=CH2, -(CH2)(4)-CH=CH2) - X-ray crystal structure of [(Bu4N)-Bu-n](3)[PW9O34((BuSiO)-Bu-t)(3)(SiCH2-CH=CH2)]

Agustin D; Coelho C; Mazeaud A; Herson P; Proust A; Thouvenot R

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Synthesis and spectroscopic characterization of the heterosilylated anions [PW9O34((BuSiO)-Bu-t)(3)(SiR)](3-) (R = -CH3, -CH=CH2, -CH2-CH=CH2, -(CH2)(4)-CH=CH2) - X-ray crystal structure of [(Bu4N)-Bu-n](3)[PW9O34((BuSiO)-Bu-t)(3)(SiCH2-CH=CH2)]

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Synthesis and spectroscopic characterization of the heterosilylated anions [PW9O34((BuSiO)-Bu-t)(3)(SiR)](3-) (R = -CH3, -CH=CH2, -CH2-CH=CH2, -(CH2)(4)-CH=CH2) - X-ray crystal structure of [(Bu4N)-Bu-n](3)[PW9O34((BuSiO)-Bu-t)(3)(SiCH2-CH=CH2)]

机译：杂硅烷化阴离子[PW9O34（（BuSiO）-Bu-t）（3）（SiR）]（3-）的合成和光谱表征（R = -CH3，-CH = CH2，-CH2-CH = CH2，-（ CH2）（4）-CH = CH2）-[（Bu4N）-Bu-n]（3）[PW9O34（（BuSiO）-Bu-t）（3）（SiCH2-CH = CH2）的X射线晶体结构]

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The reaction of the open-structure anion [PW9O34((BuSiOH)-Bu-t)(3)](3-) with RSiCl3 (R = (CH2)(n)CH=CH2 (n = 0, 1, 4)) affords [PW9O34((BuSiO)-Bu-t)(3)(SiR)](3-) heterosilylated capped hybrid compounds. These complexes were characterized by infrared spectroscopy and in solution by multinuclear (H-1, Si-29, P-31 and W-183) NMR. Crystals of [(Bu4N)-Bu-n](3)[PW9O34((BuSiO)-Bu-t)(3)Si(CH2-CH=CH2)] are orthorhombic, space group P2(1)2(1)2(1) (Ndegrees 19), with lattice constants a = 15.599(2) Angstrom, b = 23.963(5) Angstrom, c = 26.886(1) Angstrom, V = 10.050(3) Angstrom(3), and Z = 4.

机译：开放结构阴离子[PW9O34（（BuSiOH）-Bu-t）（3）]（3-）与RSiCl3（R =（CH2）（n）CH = CH2（n = 0，1，4）的反应）提供[PW9O34（（BuSiO）-Bu-t）（3）（SiR）]（3-）杂甲硅烷基化的封端杂化化合物。这些配合物通过红外光谱进行表征，并在溶液中通过多核（H-1，Si-29，P-31和W-183）NMR进行表征。 [（Bu4N）-Bu-n]（3）[PW9O34（（BuSiO）-Bu-t）（3）Si（CH2-CH = CH2）]的晶体是正交晶系，空间群P2（1）2（1） 2（1）（N度19），晶格常数a = 15.599（2）埃，b = 23.963（5）埃，c = 26.886（1）埃，V = 10.050（3）埃（3），Z = 4。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2004年第12期|共5页
作者
Agustin D; Coelho C; Mazeaud A; Herson P; Proust A; Thouvenot R;
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正文语种 eng
中图分类化学;
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polyoxometalates; tungsten; silicon; organic-inorganic hybrids; NMR (multinuclear); ORGANOSILYL DERIVATIVES; TRIVACANT TUNGSTOPHOSPHATE; GENERAL FORMULA; POLYOXOTUNGSTATES; HETEROPOLYANIONS; HYDROGELS; P-31;

机译：多金属氧酸盐;钨;硅;有机-无机杂化物;NMR（多核）;有机硅基衍生物;杂钨酸钨;一般配方;多聚钨酸盐;异氰酸酯;水合物;P-31;

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1. Synthesis and spectroscopic characterization of the heterosilylated anions [PW9O34((BuSiO)-Bu-t)(3)(SiR)](3-) (R = -CH3, -CH=CH2, -CH2-CH=CH2, -(CH2)(4)-CH=CH2) - X-ray crystal structure of [(Bu4N)-Bu-n](3)[PW9O34((BuSiO)-Bu-t)(3)(SiCH2-CH=CH2)] [J] . Agustin D, Coelho C, Mazeaud A, Zeitschrift fur Anorganische und Allgemeine Chemie . 2004,第12期

机译：杂硅烷化阴离子[PW9O34（（BuSiO）-Bu-t）（3）（SiR）]（3-）的合成和光谱表征（R = -CH3，-CH = CH2，-CH2-CH = CH2，-（ CH2）（4）-CH = CH2）-[（Bu4N）-Bu-n]（3）[PW9O34（（BuSiO）-Bu-t）（3）（SiCH2-CH = CH2）的X射线晶体结构]
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Synthesis and spectroscopic characterization of the heterosilylated anions [PW9O34((BuSiO)-Bu-t)(3)(SiR)](3-) (R = -CH3, -CH=CH2, -CH2-CH=CH2, -(CH2)(4)-CH=CH2) - X-ray crystal structure of [(Bu4N)-Bu-n](3)[PW9O34((BuSiO)-Bu-t)(3)(SiCH2-CH=CH2)]

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