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首页> 外文期刊>Chemphyschem: A European journal of chemical physics and physical chemistry >Production of RbCs Molecules in the Rovibronic Ground State via Short-Range Photoassociation to the 2 (1)Pi(1), 2 (3)Pi(1), and 3 (3)Sigma(+)(1) States
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Production of RbCs Molecules in the Rovibronic Ground State via Short-Range Photoassociation to the 2 (1)Pi(1), 2 (3)Pi(1), and 3 (3)Sigma(+)(1) States

机译:通过短程光缔合到2(1)Pi(1),2(3)Pi(1)和3(3)Sigma(+)(1)状态的Robrbronic基态的RbCs分子生产

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摘要

We report the production of ultracold (RbCs)-Rb-85-Cs-133 molecules in their rovibronic ground state X-1 sigma(+) (v=0; J=0), by short-range photoassociation (PA) to the 2 (1)(1), 2 (3)(1), and 3 (3) states. In the PA frequency range from 11650 to 12150cm(-1) (corresponding to energy levels 15500-16000cm(-1) above the bottom of the X potential), we have observed 40 sets of new PA lines. For selected PA states, we investigate vibrational branching, rotational branching, and saturation behavior. Among these 40 new PA lines, the 3 (3) (v=3) state has the highest molecule production rate of 2 x 10(3)moleculess(-1) into the rovibronic ground state.
机译:我们报告了通过短程光缔合(PA)将超冷(RbCs)-Rb-85-Cs-133分子以其旋子基态X-1 sigma(+)(v = 0; J = 0)的方式生产。 2(1)(1),2(3)(1)和3(3)状态。在从11650到12150cm(-1)的PA频率范围内(对应于X电位底部上方的能级15500-16000cm(-1)),我们已经观察到40套新的PA线。对于选定的PA状态,我们研究了振动分支,旋转分支和饱和行为。在这40条新的PA系中,3(3)(v = 3)状态进入分子波基态的分子产率最高,为2 x 10(3)moleculess(-1)。

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