Influences of amine-terminated oligomers on glass fibre-epoxy composite

摘要

Purpose - The purpose of this paper is to evaluate the mechanical properties of glass fibre reinforced epoxy composites modified with amine-terminated poly (ethylene glycol) benzoate (ATPEGB) along with their thermal stability. Design/methodology/approach - ATPEGB prepared from poly (ethylene glycol) (PEG) of different molecular weights (200, 400, 600, 4,000 and 20,000) were used as modifiers for glass fibre epoxy composite here. For toughening, 12.5 parts per hundred grams (phr) of epoxy resin of each ATPEGB was added to epoxy and pre-reacted with it. The impact, tensile and flexural strengths of modified and unmodified composite were characterised and compared for each ATPEGB. Findings - Modified resin displayed a significant improvement in fracture toughness with glass fibre over unmodified epoxy. The modification caused the formation of oligomer domains having relatively round shapes in the matrix. These oligomer domains led to improved strength and toughness due mainly to the "rubber toughening" effect in the brittle epoxy matrix. The optimum results were obtained for composite modified with ATPEGB-2 prepared from PEG of molecular weight 400. Research limitations/implications - In the present context, only 12.5 phr concentration of each ATPEGB was used to modify composite and the composites were made sing three layers of glass fibre. Besides, modification could also be done using other concentrations and more layers of glass fibre could also be used to make composite. Originality/value - The method for enhancing toughness of epoxy glass fibre composite was novel and finds numerous applications as surface coatings, casting and adhesive onto an intricate structure, etc.