首页> 外文期刊>Vibrational Spectroscopy: An International Journal devoted to Applications of Infrared and Raman Spectroscopy >Infinite impulse response filters for direct analysis of interferogram data from airborne passive Fourier transform infrared spectrometry
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Infinite impulse response filters for direct analysis of interferogram data from airborne passive Fourier transform infrared spectrometry

机译:无限脉冲响应滤波器,用于直接分析机载被动傅里叶变换红外光谱法中的干涉图数据

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摘要

Infinite impulse response (IIR) filters and support vector machines (SVMs) are applied to interferogram data to implement the automated detection of heated ethanol plumes by airborne passive Fourier transform infrared (FT-IR) spectrometry.To simulate monitoring of industrial emissions,the spectrometer is mounted in a downward-looking mode on a fixed-wing aircraft and used to detect plumes released from a portable emission stack.Both IIR and finite impulse response (FIR) filters having similar frequency responses are designed and applied to the interferogram data to extract the information associated with the ethanol C-O stretching band at 1066 cm~(-1).This study investigates the effects of distortions in the interferogram introduced by the nonlinear phase responses of the IIR filters on the ability of the SVMs to recognize ethanol.In addition,three ways to apply the filters to the interferogram are explored.These studies reveal that the phase distortion introduced by the IIR filters causes no measurable degradation in classifier performance.This allows the intrinsically lower filter order of the IIR filters to be used to reduce the length of the interferogram segment required to implement the filtering.With an independent prediction set of interferograms collected during overflights of the stack,the best SVMs miss detecting ethanol in less than 4% of the cases while achieving false detection (false positive) rates of less than 0.5%.This level of performance is accomplished with an interferogram segment of only 24 points,including those points required to implement the filtering.The ability to detect analyte vapor plumes with such a short interferogram segment is particularly advantageous in the airborne measurement because of the potential to increase the interferogram acquisition rate,thereby improving the ability to resolve ground-based targets.
机译:将无限脉冲响应(IIR)滤波器和支持向量机(SVM)应用于干涉图数据,以通过机载被动傅里叶变换红外(FT-IR)光谱仪自动检测加热的乙醇羽流。为了模拟工业排放监测,该光谱仪IIR和具有相似频率响应的有限脉冲响应(FIR)滤波器被设计并应用于干涉图数据以提取,以向下看的方式安装在固定翼飞机上,并用于检测从便携式发射烟囱释放的羽流。研究了与1066 cm〜(-1)处的乙醇CO拉伸带有关的信息。本研究调查了IIR滤波器的非线性相位响应所引入的干涉图中的畸变对SVM识别乙醇的能力的影响。研究发现了三种将滤波器应用于干涉图的方法。这些研究表明,IIR滤波器引入的相位失真会在分类器性能上没有使用可测量的降级,这允许使用IIR滤波器的本质上较低的滤波器阶数来减少实现滤波所需的干涉图片段的长度。借助在堆栈飞越过程中收集到的干涉图的独立预测集,最好的支持向量机在不到4%的情况下会漏检乙醇,而误检(假阳性)率却会低于0.5%。这一性能水平仅通过24点干涉图即可实现,包括实现这些点所需的那些点具有如此短的干涉图片段的分析物蒸气羽流的检测能力在机载测量中尤为有利,因为它有可能增加干涉图的采集速度,从而提高了分辨地面目标的能力。

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