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Preparation and adsorption properties of activated porous carbons obtained using volatile zinc templating phases

机译:挥发性锌模板相制得的活性多孔炭的制备及吸附性能

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High-surface-area activated micro/mesoporous carbons (S_(BET) ≈ 700-1900 m~2/g) were obtained by a simple synthesis method, consisting in the ZnCl2-catalyzed polymerization of furfuryl alcohol followed by the polymer pyrolysis. The ZnCl2 salt, whose quantity exceeds that necessary for the polymerization reaction, acts both as template and as activating agent during the thermal treatment. Depending on the precursor quantities, carbons with prevailing micro- or meso-porous nature were obtained. The peculiar porosities make these materials suitable for testing the adsorption of molecules of different size (methylene blue and Cy-5 cyanine), which can constitute an easy method to qualitatively identify the micro/mesoporous nature of carbon materials.
机译:通过简单的合成方法获得了高表面积的活性炭/中碳(S_(BET)≈700-1900 m〜2 / g),该方法由ZnCl2催化糠醇聚合,然后进行聚合物热解。数量超过聚合反应所需量的ZnCl2盐在热处理过程中既充当模板,又充当活化剂。取决于前体的量,获得具有普遍的微孔或中孔性质的碳。特殊的孔隙度使这些材料适合于测试不同大小的分子(亚甲基蓝和Cy-5菁)的吸附,这可以构成一种简单的方法来定性鉴定碳材料的微/介孔性质。

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