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Field induced diffusion of gold and related phase transformations in fullerenes C-60 and C-70

机译:场致富勒烯C-60和C-70中金的扩散及相关的相变

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摘要

The Au intercalation from the electrode into polycrystalline C-60 and C-70 thin films is studied by time dependent and space resolved studies of electrical resistivity measurements under oxygen free controlled atmosphere at different temperatures and applied voltages. The resistivity changes are interpreted on the basis of field induced metal diffusion with a subsequent formation of local phases MxC60, MxC70. A comparison of different features of C-60 and C-70 provides evidence that the process is sensitive to the electronic levels structure of the corresponding molecules. (C) 1998 Published by Elsevier Science Ltd. All rights reserved. [References: 5]
机译:在不同温度和施加电压下,通过无氧受控气氛下电阻率测量的时间依赖性和空间分辨研究,研究了从电极到多晶C-60和C-70薄膜中的金插层。电阻率的变化是根据场感应金属扩散以及随后形成的局部相MxC60,MxC70来解释的。 C-60和C-70不同特征的比较提供了证据,表明该过程对相应分子的电子能级结构敏感。 (C)1998由Elsevier Science Ltd.出版。保留所有权利。 [参考:5]

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