Highly dispersed and electrically conductive polycarbonate/ oxidized carbon nanofiber composites for electrostatic dissipation applications

摘要

The influence of low cost, commercially oxidized carbon nanofibers (ox-CNFs) on the morphological, thermal, mechanical and electrical properties of polycarbonate (PC) composites was examined. Using a simple solution mixing process leads to good dispersion and high packing density of CNFs in the resultant composites. The composite materials exhibit a dramatic improvement in the DC conductivity; for example, increasing from 2.36 x 10~(-14) S/m for PC to ca. 10~(-2) S/m for the composite at only 3.0 wt.% of CNFs, and exhibits a very fast static charge dissipation rate. Dynamic mechanical analysis showed a remarkable increase in storage modulus (282%) at 165 °C, compared to pure PC. Thermogravimetric analysis showed that thermal stability of the composites increased by 54 °C compared to the pure PC. To our knowledge, the measured electrical conductivity and thermal properties for PC/CNF are the highest values yet reported for PC/CNF composites at comparable loadings. The AC/DC conductivity is shown to play an important role to predict the state of dispersion.