Effect of Hydrothermal Aging on Physical and Chemical Properties of a Commercial NO_x-Storage Catalyst

摘要

Fuel consumption for NO_x trap regeneration depends on the regeneration frequency, which is a function of NO_x trap performance parameters. Hence, the impact of thermal aging must be considered in the operation strategy. For this purpose, the effect of thermal aging on the physical and chemical properties of a commercial NO_x storage/ reduction catalyst containing Pt/Pd/Rh has been investigated. After thermal treatment under various conditions, the samples were characterized using CO chemisorption measurements, X-ray diffraction (XRD), N2 physisorption, and electron microscopy. It is shown that the major impact of lean hydrothermal treatment on the catalyst activity is the continuous decrease of the specific surface area with aging temperature due to collapse of smaller pores. The noble metal nanoparticles remained highly dispersed, even after lean aging at 800 °C. In contrast, noble metal sintering represents the main aging effect of lean/rich cycling at elevated temperatures. Furthermore, XRD and selected area electron diffraction revealed a significant loss of crystallinity for the barium component in consequence of lean/rich aging treatment. However, independent from the aging treatment, no formation of mixed oxides could be observed.